The rapid generation of molecular complexity from simple starting materials is of paramount
importance in synthetic chemistry. The unique combination of high reactivity and high …

First-row transition-metal-mediated reactions constitute an important and growing area of
research due to the low cost, low toxicity, and exceptional synthetic versatility of these …

The power of cation-initiated cyclizations of polyenes for the synthesis of polycyclic
terpenoids cannot be overstated. However, a major limitation is the intolerance of many …

Indolosesquiterpenoids are a growing class of natural products that exhibit a wide range of
biological activities. Here, we report the total syntheses of xiamycin A and oridamycins A and …

This review highlights the recent applications of titanocene (III) complexes in the field of
natural product synthesis from the seminal precedents to the development of modern …

The titanocene‐catalyzed cascade cyclization of epoxypolyenes, which are easily prepared
from commercially available polyprenoids, has proven to be a useful procedure for the …

A 36‐step synthesis was carried out in automated synthesizers to provide a synthetic key
intermediate of taxol. A key step involved a microwave‐assisted alkylation reaction to …

Over the last few decades the use of radicals in synthesis has witnessed an explosive
growth through introduction of efficient chain and electron‐transfer reactions. Strained …

In the last two decades, titanocene monochloride has been postulated as a monoelectronic
transfer reagent capable of catalyzing an important variety of chemical transformations. In …

The development of Green Chemistry inevitably involves the development of green
reagents. In this review, we highlight that Cp2TiCl is a reagent widely used in radical and …