Polymerized and Colloidal Ionic Liquids─ Syntheses and Applications

Q Li, F Yan, J Texter - Chemical Reviews, 2024 - ACS Publications
The breadth and importance of polymerized ionic liquids (PILs) are steadily expanding, and
this review updates advances and trends in syntheses, properties, and applications over the …

Ion transport in polymeric ionic liquids: recent developments and open questions

V Ganesan - Molecular Systems Design & Engineering, 2019 - pubs.rsc.org
Polymeric ionic liquids (PILs) are an emerging class of materials that combine the attractive
properties of ionic liquids with the sequence complexity and mechanical characteristics of …

Ion transport in small-molecule and polymer electrolytes

CY Son, ZG Wang - The Journal of Chemical Physics, 2020 - pubs.aip.org
Solid-state polymer electrolytes and high-concentration liquid electrolytes, such as water-in-
salt electrolytes and ionic liquids, are emerging materials to replace the flammable organic …

Ion mobilities, transference numbers, and inverse Haven ratios of polymeric ionic liquids

Z Zhang, BK Wheatle, J Krajniak, JR Keith… - ACS Macro …, 2019 - ACS Publications
We probe the ion mobilities, transference numbers, and inverse Haven ratio of ionic liquids
and polymerized ionic liquids as a function of their molecular weight using a combination of …

Influence of counterion structure on conductivity of polymerized ionic liquids

JR Keith, NJ Rebello, BJ Cowen, V Ganesan - ACS Macro Letters, 2019 - ACS Publications
We performed long-time all-atom molecular dynamics simulations of cationic polymerized
ionic liquids with eight mobile counterions, systematically varying size and shape to probe …

Influence of polarizability on the structure, dynamic characteristics, and ion-transport mechanisms in polymeric ionic liquids

Z Zhang, E Zofchak, J Krajniak… - The Journal of Physical …, 2022 - ACS Publications
We used atomistic simulations and compared the prediction of three different
implementations of force fields, namely, the original full partial charge system, the scaled …

Mechanisms of ion transport in lithium salt-doped polymeric ionic liquid electrolytes

Z Zhang, AT Nasrabadi, D Aryal, V Ganesan - Macromolecules, 2020 - ACS Publications
Recent experimental results have demonstrated that polymeric ionic liquids doped with Li
salts exhibit enhanced ionic mobilities and lithium ion transference numbers with increasing …

Molecular insights into the effect of asymmetric anions on lithium coordination and transport properties in salt-doped poly (ionic liquid) electrolytes

J Li, R He, H Yuan, F Fang, G Zhou, Z Yang - Macromolecules, 2022 - ACS Publications
Poly (ionic liquid)(PIL) electrolytes are under investigations as solid-state electrolytes for all-
solid-state lithium batteries, yet the limited understanding of the ion transport mechanism in …

A multiscale simulation study of influence of morphology on ion transport in block copolymeric ionic liquids

Z Zhang, J Krajniak, V Ganesan - Macromolecules, 2021 - ACS Publications
We present results of a multiscale simulation study involving coarse-graining and reverse-
mapping steps probing at an atomistic resolution the influence of morphology on ion …

Nanoscale modelling of polymer electrolytes for rechargeable batteries

H Zhang, F Chen, J Carrasco - Energy Storage Materials, 2021 - Elsevier
Rechargeable solid-state batteries (SSBs) are of prime importance for developing the
necessary safe and efficient energy infrastructures of the future. With several inherent …