Most of the chemical and biological processes involving the fixation and transformation of
small molecules have long been exclusive for metal complexes. Meanwhile, the last …

The introduction of main group elements into conjugated scaffolds is emerging as a key
route to novel optoelectronic materials. Herein, an efficient and versatile way to synthesize …

Abstract N‐Heterocyclic carbene (NHC)‐and cyclic (alkyl)(amino) carbene (CAAC)‐
stabilized borafluorene radicals have been isolated and characterized by elemental …

Herein, we present the results of our investigations on the effect of ortho substitution of aryl
azides on the ring‐expansion reaction of boroles, five‐membered unsaturated boron …

Conjugated boron heterocycles have emerged as attractive synthetic targets due to their
potential in medicinal chemistry and as electronic materials. However, the development of …

The reactions of 9-borafluorenes with organic azides result in either the insertion of the α-
nitrogen and elimination of N2 or the insertion of the γ-nitrogen to generate the …

The utility of boron-containing compounds extends beyond the well-known applications of
boronic acids and esters in Suzuki cross-couplings and enzyme inhibition. In this selective …

Direct insertion of unsaturated substrates into a five‐membered borole ring is a useful
method to obtain valuable heterocycles containing one or more three‐coordinate boron …

Photolysis of the cyclic phosphine oligomer [PPh] 5 in the presence of pentaarylboroles
leads to the formation of 1, 2‐phosphaborines by the formal insertion of a …

Luminescent B–N containing conjugated ladder compounds are prepared by directed
electrophilic aromatic substitution. Negishi cross-coupling reaction of 2, 7-dibromo-9, 9 …