Recent trends in catalytic polymerizations
DJ Walsh, MG Hyatt, SA Miller, D Guironnet - ACS Catalysis, 2019 - ACS Publications
Polymers have become one of the largest and most important materials we use in daily life.
Their popularity has stemmed from their wide range of material properties combined with …
Their popularity has stemmed from their wide range of material properties combined with …
Catalytic living ring-opening metathesis polymerization with Grubbs' second-and third-generation catalysts
In a conventional living ring-opening metathesis polymerization (ROMP), an equal number
of ruthenium complexes to the number of polymer chains synthesized are required. This can …
of ruthenium complexes to the number of polymer chains synthesized are required. This can …
Established and emerging strategies for polymer chain‐end modification
The development of “controlled” and “living” polymerization processes with high end‐group
fidelity has enabled an unprecedented range of polymeric materials with specific chain‐end …
fidelity has enabled an unprecedented range of polymeric materials with specific chain‐end …
Highly swollen ROMP-based gels
M Yasir, K Matyjaszewski - European Polymer Journal, 2023 - Elsevier
The leakage of organic solvent during the transportation and storage is one of the major
threats to the environment. Networks/gels acting as the absorbing materials for organic …
threats to the environment. Networks/gels acting as the absorbing materials for organic …
Pulsed-Addition ROMP: Catalytic Syntheses of Heterotelechelic Polymers via Regioselective Chain Transfer Agents
Regioselective chain transfer agents are used to synthesize narrowly dispersed
heterotelechelic polymers with a 15-fold decrease in catalyst consumption using the pulsed …
heterotelechelic polymers with a 15-fold decrease in catalyst consumption using the pulsed …
The chemistry of the carbon-transition metal double and triple bond: annual survey covering the year 2016
JW Herndon - Coordination Chemistry Reviews, 2018 - Elsevier
This is a review of papers published in the year 2016 that focus on the synthesis, reactivity,
or properties of compounds containing a carbon-transition metal double or triple bond …
or properties of compounds containing a carbon-transition metal double or triple bond …
Probing the alkylidene carbene–strained alkyne equilibrium in polycyclic systems via the Fritsch–Buttenberg–Wiechell rearrangement
TE Anderson, DM Thamattoor, DL Phillips - Nature Communications, 2024 - nature.com
Strained cycloalkynes are valuable building blocks in synthetic chemistry due to their high
degree of reactivity and ability to form structurally complex scaffolds, common features of …
degree of reactivity and ability to form structurally complex scaffolds, common features of …
Functional metathesis catalyst through ring closing enyne metathesis: one pot protocol for living heterotelechelic polymers
Enyne ring closing metathesis has been used to synthesize functional group carrying
metathesis catalysts from a commercial (Ru-benzylidene) Grubbs' catalysts. The new …
metathesis catalysts from a commercial (Ru-benzylidene) Grubbs' catalysts. The new …
Efficient and facile end group control of living ring-opening metathesis polymers via single addition of functional cyclopropenes
Living ROMP has become an important technique for preparing well-controlled, highly
functional polymers; however, installing functional groups at the end of living ROMP …
functional polymers; however, installing functional groups at the end of living ROMP …
Diazoacetates as terminating agents in living ring-opening metathesis polymerization: synthesis of chain-end-functionalized polymers
X Wang, Y Sun, XQ Yao, Y Xu, J Wang - Macromolecules, 2022 - ACS Publications
We report herein a simple, efficient strategy to access diverse end-functionalized polymers
from a living ring-opening metathesis polymerization process using diazoacetates as a new …
from a living ring-opening metathesis polymerization process using diazoacetates as a new …