N-Heterocyclic Carbenes in Materials Chemistry
N-Heterocyclic carbenes (NHCs) have become one of the most widely studied class of
ligands in molecular chemistry and have found applications in fields as varied as catalysis …
ligands in molecular chemistry and have found applications in fields as varied as catalysis …
N-heterocyclic carbenes in late transition metal catalysis
S Diez-Gonzalez, N Marion, SP Nolan - Chemical Reviews, 2009 - ACS Publications
N-Heterocyclic carbenes (NHCs) are cyclic carbenes bearing at least one R-amino
substituent. 1 The most common subclasses of NHCs are represented in Chart 1. Early work …
substituent. 1 The most common subclasses of NHCs are represented in Chart 1. Early work …
IPr* an easily accessible highly hindered N-heterocyclic carbene
G Berthon-Gelloz, MA Siegler, AL Spek, B Tinant… - Dalton …, 2010 - pubs.rsc.org
IPr* an easily accessible highly hindered N-heterocyclic carbene - Dalton Transactions (RSC
Publishing) DOI:10.1039/B921894G Royal Society of Chemistry View PDF VersionPrevious …
Publishing) DOI:10.1039/B921894G Royal Society of Chemistry View PDF VersionPrevious …
[Pd(IPr*OMe)(acac)Cl]: Tuning the N-Heterocyclic Carbene in Catalytic C–N Bond Formation
S Meiries, K Speck, DB Cordes, AMZ Slawin… - …, 2013 - ACS Publications
A new N-heterocyclic ligand IPr* OMe [N, N′-bis (2, 6-bis (diphenylmethyl)-4-
methoxyphenyl) imidazol-2-ylidene] has been synthesized and compared with its earlier …
methoxyphenyl) imidazol-2-ylidene] has been synthesized and compared with its earlier …
Control of emission colour with N-heterocyclic carbene (NHC) ligands in phosphorescent three-coordinate Cu (I) complexes
VA Krylova, PI Djurovich, BL Conley… - Chemical …, 2014 - pubs.rsc.org
A series of three phosphorescent mononuclear (NHC)–Cu (I) complexes were prepared and
characterized. Photophysical properties were found to be largely controlled by the NHC …
characterized. Photophysical properties were found to be largely controlled by the NHC …
An N-heterocyclic carbene ligand with an oxalamide backbone
M Braun, W Frank, GJ Reiss, C Ganter - Organometallics, 2010 - ACS Publications
The preparation of the novel N-heterocyclic carbene ligand 3 based on an oxalamide
backbone is described. Carbene 3 is not stable as a monomeric species at ambient …
backbone is described. Carbene 3 is not stable as a monomeric species at ambient …
Bimetallic N-Heterocyclic Carbene− Iridium Complexes: Investigating Metal− Metal and Metal− Ligand Communication via Electrochemistry and Phosphorescence …
AG Tennyson, EL Rosen, MS Collins… - Inorganic …, 2009 - ACS Publications
Bimetallic [Ir (COD) Cl] and [Ir (ppy) 2](COD= 1, 5-cyclooctadiene; ppy= 2-phenylpyridyl)
complexes bridged by 1, 7-dimethyl-3, 5-diphenylbenzobis (imidazolylidene)(1), in addition …
complexes bridged by 1, 7-dimethyl-3, 5-diphenylbenzobis (imidazolylidene)(1), in addition …
Iridium complexes with monodentate N-heterocyclic carbene ligands
Monodentate N-heterocyclic carbene (NHC) ligands have been an extremely successful
class of ancillary ligands in transition metal chemistry over the last 3 decades. Particularly …
class of ancillary ligands in transition metal chemistry over the last 3 decades. Particularly …
Mild and selective H/D exchange at the β position of aromatic α-olefins by N-heterocyclic carbene-hydride-rhodium catalysts
Pacman bites selectively! Stable rhodium (III)-N-heterocyclic carbene-hydride complexes
(Pacman-like catalysts) are highly active and selective catalysts for H/D exchange at the β …
(Pacman-like catalysts) are highly active and selective catalysts for H/D exchange at the β …
[Pd (IPr*)(acac) Cl]: An Easily Synthesized, Bulky Precatalyst for C–N Bond Formation
S Meiries, A Chartoire, AMZ Slawin, SP Nolan - Organometallics, 2012 - ACS Publications
A very straightforward synthesis of [Pd (IPr*)(acac) Cl] has been developed from
commercially available Pd (acac) 2 and the easily prepared IPr*· HCl (acac …
commercially available Pd (acac) 2 and the easily prepared IPr*· HCl (acac …