Multinuclear metal complexes can effectively improve the catalytic activity of catalysts for ring-
opening polymerization (ROP) of cyclic esters. If the catalytic metal centers are close enough …

The use of multimetallic complexes is a rapidly advancing route to enhance catalyst
performance in the ring-opening polymerization of cyclic esters and ethers. Multimetallic …

Poly (lactic acid), PLA, which holds great promise as a biodegradable substitute of fossil
resource-derived polyolefins, is industrially produced by the ring-opening polymerization of …

This review highlights the ongoing developments on the ring-opening polymerization (ROP)
of lactide (LA) and caprolactone (CL) using mononuclear and dinuclear β-diketiminate-and …

Magnesium (Mg) constitutes one of the most abundant metal elements in the Earth's crust.
The spectacular career of magnesium in organic chemistry has been initiated at the …

Poly (caprolactone)(PCL) is a promising biomaterial for applications in tissue engineering,
drug delivery systems, and elastomers. However, low catalytic efficiency hinders the …

A series of gallium complexes L12Ga4Me8 (1), L22Ga4Me8 (2), and L32Ga4Me8 (3) was
synthesized by reaction of GaMe3 with Schiff base ligands L1–3H2 (L1H2= 2, 4-di-tert-butyl …

Tetranuclear Schiff‐base complexes L1–32Ga4 (t‐Bu) 8 1–3 are highly active and selective
(> 99%) catalyst in the alternating ring‐opening copolymerization (ROCOP) of epoxides and …

Currently, there is a growing interest in the development of suitable methods for the
preparation of eco-friendly and biocompatible materials in order to increase environmental …

A series of heteroleptic β-ketoimine magnesium complexes L1L′ 1 Mg2Cp*(1),
L22Mg2Cp2 (2), L12Mg2 (OAr) 2 (3 and 4), and L22Mg2 (OAr) 2 (5 and 6)(L1 …