Emerging trends in spin crossover (SCO) based functional materials and devices

KS Kumar, M Ruben - Coordination Chemistry Reviews, 2017 - Elsevier
The design and synthesis of functional molecules with controllable properties are at the
forefront of modern materials chemistry research due to their diverse applicability, especially …

[HTML][HTML] Spin-crossover nanoparticles and nanocomposite materials

L Salmon, L Catala - Comptes Rendus Chimie, 2018 - Elsevier
This contribution reports on the state of the art of the elaboration and the application of
nanoparticles (NPs) and nanohybrid/nanocomposite materials based on spin-crossover …

Finite size effects on the switching dynamics of spin‐crossover thin films photoexcited by a femtosecond laser pulse

K Ridier, AC Bas, V Shalabaeva, W Nicolazzi… - Advanced …, 2019 - Wiley Online Library
Using ultrafast optical absorption spectroscopy, the room‐temperature spin‐state switching
dynamics induced by a femtosecond laser pulse in high‐quality thin films of the molecular …

Dynamical limits for the molecular switching in a photoexcited material revealed by X-ray diffraction

A Volte, C Mariette, R Bertoni, M Cammarata… - Communications …, 2022 - nature.com
Time-resolved studies with temporal resolution that separate molecular level dynamics from
macroscopic changes, allow clear distinction between the time scales of the different …

Size and Surface Effects in the Ultrafast Dynamics of Strongly Cooperative Spin‐Crossover Nanoparticles

TN Haddock, T Delgado, M Alías‐Rodríguez… - Small, 2024 - Wiley Online Library
Cooperative photoinduced switching of molecular materials at the nanoscale is still in its
infancy. Strongly cooperative spin‐crossover nanomaterials are arguably the best …

[HTML][HTML] Polynuclear Fe (II) complexes: Di/trinuclear molecules and coordination networks

JRG Mascarós, G Aromí, M Darawsheh - Comptes Rendus Chimie, 2018 - Elsevier
We review here the recent progress made in the synthesis of spin crossover (SCO) Fe (II)
coordination complexes with two or three metal atoms, as well as coordination polymers …

Light-induced spin state switching in copper (ii)-nitroxide-based molecular magnet at room temperature

X Dong, M Lorenc, EV Tretyakov… - The Journal of …, 2017 - ACS Publications
Molecular magnets Cu (hfac) 2LR exhibit an unusual type of photoinduced
magnetostructural switching in exchange-coupled copper (II)-nitroxide clusters. Such …

Spin crossover and cooperativity in nanocrystalline [Fe (pyrazine) Pt (CN) 4] thin films deposited by matrix-assisted laser evaporation

D Maskowicz, M Sawczak, AC Ghosh… - Applied Surface …, 2021 - Elsevier
Thin film structures with controlled functionalities are critical to exploit the exceptional
application capacity of spin crossover complexes. Here, we report spin crossover (SCO) in …

Temperature dependence of the cooperative out-of-equilibrium elastic switching in a spin-crossover material

R Bertoni, E Collet, H Cailleau, ML Boillot… - Physical Chemistry …, 2019 - pubs.rsc.org
We present a study of a molecular material,[FeIII (3-MeO-SalEen) 2] PF6, undergoing
cooperative reversible photo-induced transition between low-spin state and high-spin state …

Spin-Resolved Band Structure of Hoffman Clathrate [Fe(pz)2Pt(CN)4] as an Essential Tool to Predict Optical Spectra of Metal–Organic Frameworks

A Olejnik, W Kopec, D Maskowicz… - ACS Applied Materials & …, 2023 - ACS Publications
Paramount spin-crossover properties of the 3D-Hoffman metalorganic framework (MOF)[Fe
(pz) 2Pt (CN) 4] are generally described on the basis of the ligand field theory, which …