[HTML][HTML] Sandwich d/f Heterometallic Complexes [(Ln(hfac)3)2M(acac)3] (Ln = La, Pr, Sm, Dy and M = Co; Ln = La and M = Ru)

C Grechi, S Carlotto, M Guelfi, S Samaritani, L Armelao… - Molecules, 2024 - mdpi.com
Sandwich d/f heterometallic complexes [(Ln (hfac) 3) 2M (acac) 3](Ln= La, Pr, Sm, Dy and
M= Co; Ln= La and M= Ru) were prepared in strictly anhydrous conditions reacting the …

Understanding Stabilization Factors in Heterodinuclear Ln–Al Complexes from DFT Simulations on Thermochemistry Data: A Counterintuitive Conclusion

S Carlotto, L Babetto, L Bellucci, G Bottaro… - Inorganic …, 2024 - ACS Publications
This study validates a computational protocol to predict the stability of heterodinuclear
complexes by varying ligands on both moieties and analyzing the reaction Gibbs free …

Aluminium 8-Hydroxyquinolinate N-Oxide as a Precursor to Heterometallic Aluminium–Lanthanide Complexes

E Gallo, L Bellucci, S Carlotto, G Bottaro, L Babetto… - Molecules, 2024 - mdpi.com
A reaction in anhydrous toluene between the formally unsaturated fragment [Ln (hfac)
3](Ln3+= Eu3+, Gd3+ and Er3+; Hhfac= hexafluoroacetylacetone) and [Al (qNO) 3](HqNO …