Equilibrium gels of limited valence colloids

F Sciortino, E Zaccarelli - Current opinion in colloid & interface science, 2017 - Elsevier
Gels are low-packing arrested states of matter which are able to support stress. On cooling,
limited valence colloidal particles form open networks stabilized by the progressive increase …

Developments in understanding and controlling self assembly of DNA-functionalized colloids

L Di Michele, E Eiser - Physical Chemistry Chemical Physics, 2013 - pubs.rsc.org
In this article we review the latest achievements in understanding and controlling DNA-
mediated interactions between colloidal particles. We report the results of experiments …

Liquids more stable than crystals in particles with limited valence and flexible bonds

F Smallenburg, F Sciortino - Nature Physics, 2013 - nature.com
All liquids (except helium owing to quantum effects) crystallize at low temperatures, forming
ordered structures. The competition between disorder, which stabilizes the liquid phase, and …

Multistep kinetic self-assembly of DNA-coated colloids

L Di Michele, F Varrato, J Kotar, SH Nathan… - Nature …, 2013 - nature.com
Equilibrium self-assembly relies on the relaxation of disordered mixtures of building blocks
towards an ordered ground state. The main drawback of this traditional approach lies in the …

Patchy particle model for vitrimers

F Smallenburg, L Leibler, F Sciortino - Physical review letters, 2013 - APS
Vitrimers—a recently invented new class of polymers—consist of covalent networks that can
rearrange their topology via a bond shuffling mechanism, preserving the total number of …

Predicting crystals of Janus colloids

T Vissers, Z Preisler, F Smallenburg… - The Journal of …, 2013 - pubs.aip.org
We present a numerical study on the phase diagram for a simple model of Janus colloids,
including ordered and disordered structures. Using a range of techniques, we generate a set …

Aggregation dynamics, structure, and mechanical properties of bigels

L Di Michele, D Fiocco, F Varrato, S Sastry, E Eiser… - Soft matter, 2014 - pubs.rsc.org
Recently we have introduced bigels, inter-penetrating gels made of two different colloidal
species. Even if particles with simple short-range isotropic potential are employed, the …

Chemically orthogonal three‐patch microparticles

S Rahmani, S Saha, H Durmaz, A Donini… - Angewandte Chemie …, 2014 - Wiley Online Library
Compared to two‐dimensional substrates, only a few methodologies exist for the spatially
controlled decoration of three‐dimensional objects, such as microparticles. Combining …

Interpenetrating gels in binary suspensions of DNA nanostars

E Lattuada, T Pietrangeli, F Sciortino - The Journal of Chemical …, 2022 - pubs.aip.org
We experimentally investigate the equilibrium gel formation in a binary mixture of DNA
nanostars. The binding rules, encoded in the DNA sequence of the nanostar binding ends …

Phase behaviour of pure and mixed patchy colloids—Theory and simulation

PIC Teixeira, JM Tavares - Current Opinion in Colloid & Interface Science, 2017 - Elsevier
We review the phase behaviour of pure and mixed patchy colloids, as revealed (mostly) by
theory and computer simulation. These experimentally-realisable systems are excellent …