X-ray Raman scattering: a hard X-ray probe of complex organic systems

R Georgiou, CJ Sahle, D Sokaras, S Bernard… - Chemical …, 2022 - ACS Publications
This paper provides a review of the characterization of organic systems via X-ray Raman
scattering (XRS) and a step-by-step guidance for its application. We present the …

Looking inside a Ni-Fe/MgAl2O4 catalyst for methane dry reforming via Mössbauer spectroscopy and in situ QXAS

V De Coster, NV Srinath, SA Theofanidis, L Pirro… - Applied Catalysis B …, 2022 - Elsevier
The evolution of the constituents of an 8 wt% Ni-5 wt% Fe/MgAl 2 O 4 catalyst for dry
reforming of methane (DRM) is monitored by in situ quick X-ray absorption spectroscopy …

[HTML][HTML] Advancements in biomass gasification and catalytic tar-cracking technologies

Y Niu, Z Chi, M Li, J Du, F Han - Materials Reports: Energy, 2024 - Elsevier
Biomass, heralded as sustainable “green coal”, plays a crucial role in energy conservation
and achieving “dual carbon” objectives through clean conversion. This paper reviews …

Evolution of Low Z-Elements in a Ni/MgFeAlO4 Catalyst during Reaction: Insight from In Situ XRS

S Kumar Das, L D'ooghe, NV Srinath… - ACS …, 2024 - ACS Publications
Ni/MgFeAlO4 displays promising activity and stability in the dry reforming of methane. In
order to establish a correlation between its performance and structural changes, an in-depth …

Dual-Element Modulation Excitation XAS to Probe the Redox Surface Chemistry of a Ni–Fe Dry Reforming Catalyst

V De Coster, NV Srinath, P Yazdani, H Poelman… - ACS …, 2023 - ACS Publications
Fe and Ni K edge CO2/H2 modulation excitation X-ray absorption spectroscopy (MEXAS)
was performed to gain insights into the CO2/H2 redox behavior of Ni and Fe species within …

Catalyst-enhanced autothermal chemical looping reforming: Intrinsic SMR kinetics and numerical simulation

Z He, F Minette, J De Wilde - Energy Conversion and Management, 2023 - Elsevier
In this work, we propose a catalyst-enhanced autothermal chemical looping reforming (CE-
aCLR) to address the environmental concerns associated with toxic Ni-based oxygen carrier …

X-ray Spectroscopy of (Ba,Sr,La)(Fe,Zn,Y)O3−δ Identifies Structural and Electronic Features Favoring Proton Uptake

G Raimondi, F Giannici, A Longo, R Merkle… - Chemistry of …, 2020 - ACS Publications
Mixed protonic–electronic conducting oxides are key functional materials for protonic
ceramic fuel cells. Here,(Ba, Sr, La)(Fe, Zn, Y) O3− δ perovskites are comprehensively …

Intensifying blue hydrogen production by in situ CO2 utilisation

V Singh, LC Buelens, H Poelman, M Saeys… - Journal of CO2 …, 2022 - Elsevier
The current production of hydrogen, predominantly through steam methane reforming,
causes up to 3% of global CO 2 emissions. Since hydrogen is expected to play an …

Electronic modifications in (Ba, La)(Fe, Zn, Y) O 3− δ unveiled by oxygen K-edge X-ray Raman scattering

G Raimondi, A Longo, F Giannici, R Merkle… - Journal of Materials …, 2022 - pubs.rsc.org
Oxides with mixed protonic–electronic conductivity are relevant as oxygen electrodes for
protonic ceramic fuel cells and electrolyzers. We investigate the modification of the …

Carbon monoxide production using a steel mill gas in a combined chemical looping process

V Singh, LC Buelens, H Poelman, M Saeys… - Journal of Energy …, 2022 - Elsevier
Up to 9% of the global CO 2 emissions come from the iron and steel industry. Here, a
combined chemical looping process to produce CO, a building block for the chemical …