Herein we report a photoredox/nickel-catalyzed cross-coupling of aryl bromides with 1, 1, 1,
3, 3, 3-hexafluoroisopropanol for the construction of hexafluoroisopropyl aryl ethers. The …

Herein, we report the first allenylic alkylation with bench-stable aliphatic amine-derived
Katritzky salts via photoredox/nickel dual-catalyzed reductive deaminative cross-electrophile …

This manuscript details the development of an asymmetric variant for the Ni-photoredox α-
arylation of tetrahydrofuran (THF), which was originally reported in a racemic fashion by …

There is growing demand for the utilization of first-row transition metal complexes in light-
driven processes instead of their conventional noble metal counterparts due to the greater …

The mechanism of visible light-driven Ni–C (aryl) bond homolysis in (2, 2′-bipyridine) NiII
(aryl)(halide) complexes, which play a crucial role in metallaphotoredox catalysis for cross …

Despite conceptual breakthroughs in dual photoredox-and nickel-catalyzed arylation of
radicals, the approach remains largely limited to localized C-centered radicals. Here, we …

This study presents a Ni‐photoredox method for indole N‐arylation, broadening the range of
substrates to include indoles with unprotected C3‐positions and base‐sensitive groups …

Bipyridine ligands have been extensively employed in nickel catalysis, with ligand
modifications focused on steric or electronic tuning. In this work, we explore modifications …

Sulfonyl hydrazides are disclosed as versatile radical precursors as exemplified with seven
new C–C bond forming, redox neutral cross-couplings with:(1) unsaturated olefins,(2) alkyl …

This manuscript details the development of an asymmetric variant for the Ni-photoredox α-
arylation of tetrahydrofuran (THF), which was originally reported in a racemic fashion by …