Sesqui-, di-, and triterpenoids as chemosystematic markers in extant conifers—a review

A Otto, V Wilde - The Botanical Review, 2001 - Springer
Chemosystematics is a common tool in systematics and taxonomy of extant plants.
Terpenoids have been found to be especially valuable for chemosystematic investigations of …

Chemical transformations of characteristic hop secondary metabolites in relation to beer properties and the brewing process: A review

B Steenackers, L De Cooman, D De Vos - Food Chemistry, 2015 - Elsevier
The annual production of hops (Humulus lupulus L.) exceeds 100,000 mt and is almost
exclusively consumed by the brewing industry. The value of hops is attributed to their …

Biosynthesis of the Sesquiterpene Botrydial in Botrytis cinerea. Mechanism and Stereochemistry of the Enzymatic Formation of Presilphiperfolan-8β-ol

CM Wang, R Hopson, X Lin… - Journal of the American …, 2009 - ACS Publications
Presilphiperfolan-8β-ol synthase, encoded by the BcBOT2 gene from the necrotrophic plant
pathogen Botrytis cinerea, catalyzes the multistep cyclization of farnesyl diphosphate (2) to …

[HTML][HTML] Rational reprogramming of the sesquiterpene synthase BcBOT2 yields new terpenes with presilphiperfolane skeleton

V Nikolaiczyk, J Irwan, T Nguyen, J Fohrer… - Catalysis Science & …, 2023 - pubs.rsc.org
Computer-aided rational design of the substrate binding pocket of sesquiterpene synthases
BcBOT2 from Botrytis cinerea yielded FPP cyclization products with presilphiperfolane …

New β-Caryophyllene-Derived Terpenoids from the Soft Coral Sinularia nanolobata

AF Ahmed, JH Su, RT Shiue, XJ Pan… - Journal of Natural …, 2004 - ACS Publications
Two new norsesquiterpenoids, nanonorcaryophyllenes A (1) and B (2), two new
diterpenoids, nanolobatins A (3) and B (4), and a novel norditerpenoid, nanolobatin C (5) …

Biosynthesis and chemical synthesis of presilphiperfolanol natural products

AY Hong, BM Stoltz - Angewandte Chemie International Edition, 2014 - Wiley Online Library
Presilphiperfolanols constitute a family of biosynthetically important sesquiterpenes which
can rearrange to diverse sesquiterpenoid skeletons. While the origin of these natural …

Antimalarial Isocyano and Isothiocyanato Sesquiterpenes with Tri- and Bicyclic Skeletons from the Nudibranch Phyllidia ocellata

AM White, GK Pierens, T Skinner-Adams… - Journal of natural …, 2015 - ACS Publications
Five new isocyano/isothiocyanato sesquiterpenes (1–5) with tri-or bicyclic carbon skeletons
have been characterized from Australian specimens of the nudibranch Phyllidia ocellata …

Stereochemistry of 14-hydroxy-β-caryophyllene and related compounds

AF Barrero, J Molina, JE Oltra, J Altarejos, A Barragán… - Tetrahedron, 1995 - Elsevier
The isomerization of β-caryophyllene (3), under treatment with SeO2, is described. Chemical
correlations, between 3 14--hydroxy-β-caryophylllene (6z) from Juniperus oxycedrus, are …

11-Oxygenated cytotoxic 8, 9-secokauranes from a New Zealand liverwort, Lepidolaena taylorii

NB Perry, EJ Burgess, SH Baek, RT Weavers, W Geis… - Phytochemistry, 1999 - Elsevier
Four new cytotoxic 8, 9-secokauranes have been identified from the liverwort Lepidolaena
taylorii. The 11-oxygenation found in three of these has not been encountered in the 8, 9 …

Solvolysis of caryophyllen-8β-yl derivatives: biomimetic rearrangement− cyclization to 12-Nor-8α-presilphiperfolan-9β-ol

S Shankar, RM Coates - The Journal of Organic Chemistry, 1998 - ACS Publications
The solvolyses of caryophyllen-8β-yl p-nitrobenzoate (14-O p NB) and 15-norcaryophyllen-
8β-yl tosylate (15-OTs) were investigated as potential model reactions for the biogenesis of …