Protonic ceramic electrochemical cells (PCECs) have been intensively studied as the
technology that can be employed for power generation, energy storage, and sustainable …

The functionalization of coordinated dinitrogen to form nitrogen–element bonds en route to
nitrogen-containing molecules is a long-standing challenge in chemical synthesis. The …

Mechanistic insight into the catalytic production of ammonia from dinitrogen is needed to
improve the synthesis of this vital molecule. Here we study the use of samarium diiodide …

Despite advances in the development of molecular catalysts capable of reducing dinitrogen
to ammonia using proton donors and chemical reductants, few molecular electrocatalysts …

The direct scission of the triple bond of dinitrogen (N2) by a metal complex is an alluring
entry point into the transformation of N2 to ammonia (NH3) in molecular catalysis. Reported …

Local electric fields can alter energy landscapes to impart enhanced reactivity in enzymes
and at surfaces. Similar fields can be generated in molecular systems using charged …

Although metal complexes are known to split dinitrogen at ambient temperature and
pressure, the synthesis of ammonia from these compounds with H2 as the terminal reductant …

Nitrogen fixation using homogeneous transition metal complexes under mild reaction
conditions is a challenging topic in the field of chemistry. Several successful examples of the …

Ammonia synthesis from N, N, O, O-supported manganese (V) nitrides and 9, 10-
dihydroacridine using proton-coupled electron transfer and visible light irradiation in the …

Mo complexes are currently the most active catalysts for nitrogen fixation under ambient
conditions. In comparison, tungsten platforms are scarcely examined. For active catalysts …