Electrochemical Conversion of CO2 to Syngas with Palladium-Based Electrocatalysts

BM Tackett, JH Lee, JG Chen - Accounts of Chemical Research, 2020 - ACS Publications
Conspectus Electrocatalytic reduction of CO2 is a desirable method to produce valuable
products from CO2. One of the main research challenges for electrocatalysis that produces …

Advances in hydrogen/deuterium exchange mass spectrometry and the pursuit of challenging biological systems

EI James, TA Murphree, C Vorauer, JR Engen… - Chemical …, 2021 - ACS Publications
Solution-phase hydrogen/deuterium exchange (HDX) coupled to mass spectrometry (MS) is
a widespread tool for structural analysis across academia and the biopharmaceutical …

Atomically dispersed Ru oxide catalyst with lattice oxygen participation for efficient acidic water oxidation

N Yao, H Jia, J Zhu, Z Shi, H Cong, J Ge, W Luo - Chem, 2023 - cell.com
The development of highly efficient and stable electrocatalysts toward the acidic oxygen
evolution reaction (OER) is essential for the practical application of proton-exchange …

Organometallic half-sandwich iridium anticancer complexes

Z Liu, A Habtemariam, AM Pizarro… - Journal of medicinal …, 2011 - ACS Publications
The low-spin 5d6 IrIII organometallic half-sandwich complexes [(η5-Cpx) Ir (XY) Cl] 0/+,
Cpx= Cp*, tetramethyl (phenyl) cyclopentadienyl (Cpxph), or tetramethyl (biphenyl) …

Unraveling tetrazine-triggered bioorthogonal elimination enables chemical tools for ultrafast release and universal cleavage

JCT Carlson, H Mikula… - Journal of the American …, 2018 - ACS Publications
Recent developments in bond cleavage reactions have expanded the scope of
bioorthogonal chemistry beyond click ligation and enabled new strategies for probe …

Trimethylamine N-oxide stabilizes proteins via a distinct mechanism compared with betaine and glycine

YT Liao, AC Manson, MR DeLyser… - Proceedings of the …, 2017 - National Acad Sciences
We report experimental and computational studies investigating the effects of three
osmolytes, trimethylamine N-oxide (TMAO), betaine, and glycine, on the hydrophobic …

pH-dependent random coil 1H, 13C, and 15N chemical shifts of the ionizable amino acids: a guide for protein pK a measurements

G Platzer, M Okon, LP McIntosh - Journal of biomolecular NMR, 2014 - Springer
The p K a values and charge states of ionizable residues in polypeptides and proteins are
frequently determined via NMR-monitored pH titrations. To aid the interpretation of the …

Alkyne-tagged Raman probes for local environmental sensing by hydrogen–deuterium exchange

X Bi, K Miao, L Wei - Journal of the American Chemical Society, 2022 - ACS Publications
Alkyne-tagged Raman probes have shown high promise for noninvasive and sensitive
visualization of small biomolecules to understand their functional roles in live cells …

[HTML][HTML] Identification of key structural features of the elusive Cu–Aβ complex that generates ROS in Alzheimer's disease

C Cheignon, M Jones, E Atrián-Blasco, I Kieffer… - Chemical …, 2017 - pubs.rsc.org
Oxidative stress is linked to the etiology of Alzheimer's disease (AD), the most common
cause of dementia in the elderly. Redox active metal ions such as copper catalyze the …

Tuning the reactivity of osmium (II) and ruthenium (II) arene complexes under physiological conditions

AFA Peacock, A Habtemariam… - Journal of the …, 2006 - ACS Publications
The OsII arene ethylenediamine (en) complexes [(η6-biphenyl) Os (en) Cl][Z], Z= BPh4 (4)
and BF4 (5), are inactive toward A2780 ovarian cancer cells despite 4 being isostructural …