Recent progress in transition metal-free C-heteroatom bond formation by functionalization of CH bond in imidazole-fused heterocycles

X Xu, D Chen, Z Wang - Chinese Journal of Organic Chemistry, 2019 - sioc-journal.cn
Recently, the direct incorporation of heteroatom into imidazole-fused heterocycles through
transition metal-free CH functionalization has rapidly been advanced and become an eco …

Sodium salts (NaI/NaBr/NaCl) for the halogenation of imidazo-fused heterocycles

R Semwal, C Ravi, R Kumar, R Meena… - The Journal of Organic …, 2018 - ACS Publications
We report herein an effective method for the halogenation of imidazo-fused heterocycles
using readily available sodium salts (NaCl/NaBr/NaI) as halogen source and K2S2O8 (or) …

Iodine-Catalyzed Selenylation of 2H-Indazole

A Dey, A Hajra - The Journal of Organic Chemistry, 2019 - ACS Publications
A metal-free, environmentally friendly protocol for the arylselenylation of 2 H-indazole has
been developed using a catalytic amount of I2 under ambient conditions. A number of 3 …

Temperature-controlled chalcogenation and chalcogenocyanation of imidazopyridines in water under transition metal-free conditions

YS Zhu, Y Xue, W Liu, X Zhu, XQ Hao… - The Journal of Organic …, 2020 - ACS Publications
A sustainable and transition metal-free approach for C3 chalcogenation and
chalcogenocyanation of imidazopyridines with KXCN (X= S or Se) has been developed …

Regioselective C3–H Alkylation of Imidazopyridines with Donor–Acceptor Cyclopropanes

O Dalkilic, O Turbedaroglu, F Lafzi… - The Journal of Organic …, 2023 - ACS Publications
Alkylated imidazopyridines are crucial structures for medicinal chemistry. Here, an efficient
method for the C3–H alkylation of imidazopyridines was devised. Under Lewis acid …

Visible-light-induced phosphorylation of imidazo-fused heterocycles under metal-free conditions

F Gao, K Sun, XL Chen, T Shi, XY Li… - The Journal of …, 2020 - ACS Publications
A metal-free and base-free procedure for the phosphorylation of imidazo [1, 2-a] pyridines
with phosphine oxides under the irradiation of visible light at room temperature in green …

Copper-catalyzed double thiolation to access sulfur-bridged imidazopyridines with isothiocyanate

LL Tian, S Lu, ZH Zhang, EL Huang… - The Journal of …, 2019 - ACS Publications
A copper (I)-catalyzed sulfur-bridged dimerization of imidazopyridines has been developed
using isothiocyanate as the sulfur source. This method enables a switchable synthesis of bis …

Organocatalytic dehydration of fructose-based carbohydrates into 5-hydroxymethylfurfural in the presence of a neutral inner salt

H Ma, B Yu, C Yue, Y Qiao, N Li, T Cai, J Teng - ACS omega, 2023 - ACS Publications
A series of organic sulfonate inner salts, viz., aprotic imidazolium-and pyridinium-based
zwitterions bearing sulfonate groups (− SO3–), were synthesized for the catalytic conversion …

Novel acidic ionic liquid [BEMIM][HSO4]: A highly efficient and recyclable catalyst for the synthesis of bis-indolyl methane derivatives

R Athavale, S Gardi, F Choudhary, D Patil… - Applied Catalysis A …, 2024 - Elsevier
The novel acidic ionic liquid [BEMIM][HSO 4] was prepared and characterized by FT-IR, 1 H
NMR, 13 C NMR, DEPT-135, LC-Mass, and elemental analysis techniques. It was examined …

Electrochemical oxidative iodination of imidazo[1,2-a]pyridines using NaI as iodine source

JW Park, YH Kim, DY Kim - Synthetic Communications, 2020 - Taylor & Francis
An electrochemical oxidative iodination of imidazo [1, 2-a] pyridines is achieved in this study.
This reaction utilizes NaI as an iodine source and a supporting electrolyte under metal-free …