Advances in the Pd-catalyzed synthesis of C-glycosides and branched sugars are
summarized herein and the strategies are categorized based on named reactions or types of …

In recent years, C-glycosides have emerged as significant building blocks for many naturally
occurring alkaloids and pharmaceutically active drug molecules. Therefore, significant …

Bi (OTf) 3 promoted direct and highly stereoselective glycosylation of “disarmed” and
“armed” glycals to synthesize 2-deoxyglycosides has been reported. The tunable and …

Aryl-C-glycosides, of both synthetic and natural origin, are of great significance in medicinal
chemistry owing to their unique structures and stability towards enzymatic and chemical …

A highly efficient coupling of glycosyl stannanes and sulfonium salts enabled by synergistic
Pd/Cu catalysis is disclosed, facilitating the construction of C-aryl/alkenyl glycals under mild …

An efficient and eco‐friendly method has been developed for the preparation of
functionalized 3‐(S)‐arylthioindoles in good to excellent yields from indoles and aryl thiols in …

C-1 Glycals serve as pivotal intermediates in synthesizing diverse C-glycosyl compounds
and natural products, necessitating the development of concise, efficient and user-friendly …

Here, we report an efficient Pd (II)-catalyzed Heck coupling reaction utilizing modular and
readily available thianthrenium salts. The tunability and ease of thianthrenium salts …

Oxoglycals are versatile building blocks with extensive applications in glycochemistry,
organic, and bio-organic sciences. They serve as powerful synthons, enabling the …

C-Glycosides represent a privileged class of carbohydrates, which exhibit remarkable
biological and pharmaceutical activities. Transition metal-catalyzed cross coupling reaction …