Proton-coupled electron transfer (PCET) plays an essential role in a wide range of
electrocatalytic processes. A vast array of theoretical and computational methods have been …

Pendant amines play an invaluable role in chemical reactivity, especially for molecular
catalysts based on earth-abundant metals. As inspired by [FeFe]-hydrogenases, which …

The synthesis of renewable fuels from abundant water or the greenhouse gas CO2 is a
major step toward creating sustainable and scalable energy storage technologies. In the last …

Reduction of acids to molecular hydrogen as a means of storing energy is catalyzed by
platinum, but its low abundance and high cost are problematic. Precisely controlled delivery …

Molecular electrocatalysts can play an important role in energy storage and utilization
reactions needed for intermittent renewable energy sources. This manuscript describes …

One of the most appealing strategies to address the problems of global warming and energy
shortage is to develop clean and sustainable energy source. To this end, considerable …

A series of water-soluble molecular cobalt complexes of tetraazamacrocyclic ligands are
reported for the electrocatalytic production of H2 from pH 2.2 aqueous solutions. The …

Generation of hydrogen by reduction of two protons by two electrons can be catalysed by
molecular electrocatalysts. Determination of the thermodynamic driving force for elimination …

A nickel (II) porphyrin Ni‐P (P= porphyrin) bearing four meso‐C6F5 groups to improve
solubility and activity was used to explore different hydrogen‐evolution‐reaction (HER) …

Several H− H bond forming pathways have been proposed for the hydrogen evolution
reaction (HER). Revealing these HER mechanisms is of fundamental importance for the …