Atomic and molecular electron affinities: photoelectron experiments and theoretical computations
JC Rienstra-Kiracofe, GS Tschumper… - Chemical …, 2002 - ACS Publications
The energy difference between an uncharged species and its negative ion, referred to as an
electron affinity (EA), is an important property of atoms and molecules. Negative ions, or …
electron affinity (EA), is an important property of atoms and molecules. Negative ions, or …
Thermionic emission from clusters
JU Andersen, E Bonderup… - Journal of Physics B …, 2002 - iopscience.iop.org
We discuss the interpretation of delayed electron emission from excited clusters as a
statistical process analogous to thermionic emission from a hot filament. We argue that …
statistical process analogous to thermionic emission from a hot filament. We argue that …
Bonding within the Endohedral Fullerenes Sc3N@C78 and Sc3N@C80 as Determined by Density Functional Calculations and Reexamination of the Crystal Structure of {Sc3N@C78}·Co(OEP)}·1.5(C …
JM Campanera, C Bo, MM Olmstead… - The Journal of …, 2002 - ACS Publications
Density functional calculations have been performed on Sc3N@ C80 and Sc3N@ C78 to
examine the bonding between the scandium atoms and the fullerene cage. The …
examine the bonding between the scandium atoms and the fullerene cage. The …
High-resolution photoelectron imaging of cold C60− anions and accurate determination of the electron affinity of C60
High-resolution photoelectron imaging and spectroscopy of cold| ${\rm C} _ {60}^-$| C 60−
anions are reported using a newly built photoelectron imaging apparatus coupled with an …
anions are reported using a newly built photoelectron imaging apparatus coupled with an …
Vibrational cooling in a cold ion trap: Vibrationally resolved photoelectron spectroscopy of cold C60− anions
We demonstrate vibrational cooling of anions via collisions with a background gas in an ion
trap attached to a cryogenically controlled cold head (10–400 K). Photoelectron spectra of …
trap attached to a cryogenically controlled cold head (10–400 K). Photoelectron spectra of …
Relationship between the electron affinities and half-wave reduction potentials of fullerenes, aromatic hydrocarbons, and metal complexes
Differences in energy for neutral molecule and negative ions upon going from the gas phase
to solution,—AAGsoi, have been calculated from gas phase electron affinities and half-wave …
to solution,—AAGsoi, have been calculated from gas phase electron affinities and half-wave …
[HTML][HTML] Perfluoroalkylfullerenes
OV Boltalina, AA Popov, IV Kuvychko… - Chemical …, 2015 - ACS Publications
Perfluoroalkylfullerenes | Chemical Reviews ACS ACS Publications C&EN CAS Find my
institution Log In Chemical Reviews ACS Publications. Most Trusted. Most Cited. Most Read …
institution Log In Chemical Reviews ACS Publications. Most Trusted. Most Cited. Most Read …
Electrochemical, Spectroscopic, and DFT Study of C60(CF3)n Frontier Orbitals (n = 2−18): The Link between Double Bonds in Pentagons and Reduction …
AA Popov, IE Kareev, NB Shustova… - Journal of the …, 2007 - ACS Publications
The frontier orbitals of 22 isolated and characterized C60 (CF3) n derivatives, including
seven reported here for the first time, have been investigated by electronic spectroscopy (n …
seven reported here for the first time, have been investigated by electronic spectroscopy (n …
Density Functional Calculations of the 13C NMR Chemical Shifts in (9,0) Single-Walled Carbon Nanotubes
E Zurek, J Autschbach - Journal of the American Chemical Society, 2004 - ACS Publications
The electronic structure and 13C NMR chemical shift of (9, 0) single-walled carbon
nanotubes (SWNTs) are investigated theoretically. Shielding tensor components are also …
nanotubes (SWNTs) are investigated theoretically. Shielding tensor components are also …
Delayed ionization and fragmentation en route to thermionic emission: Statistics and dynamics
EEB Campbell, RD Levine - Annual review of physical chemistry, 2000 - annualreviews.org
Thermionic emission is discussed as a long time (microseconds) decay mode of energy-rich
large molecules, metallic and metcar clusters, and fullerenes. We review what is known and …
large molecules, metallic and metcar clusters, and fullerenes. We review what is known and …