Organoborons play a crucial role in organic synthesis, easing the construction of C–C and C–
X bonds which in turn sensitize C–H borylation reactions. In the consideration of inert C …

An iridium-catalyzed ortho C–H borylation reaction directed by cyclic dithioacetal moiety is
disclosed. A series of borylation products were obtained in moderate to good yields under …

Iridium-catalyzed C–H borylation of THF was theoretically investigated as example of sp3 C–
H functionalization. DFT computations show that β-regioselective borylation occurs more …

Methane borylation catalyzed by Cp* M (Bpin) n (M= Ru or Rh; HBpin= pinacolborane; n= 2
or 3) and (TMPhen) Ir (Bpin) 3 (TMPhen= 3, 4, 7, 8-tetramethyl-1, 10-phenanthroline) was …

Burgeoning interest in distal functionalization of aryl C–H bonds led to the development of
iridium-catalyzed borylation reactions. The significance and inadequate mechanistic …

The recently developed iridium-catalyzed C (sp3)–H borylation with the 2, 2′-
dipyridylarylmethane ligand provides a highly efficient catalytic system for alkane borylation …

Transition-metal-catalyzed C (sp3)–H bond activation in aliphatic compounds are of current
interest. Lack of mechanistic insights on Ni-catalyzed C (sp3)–H activation using 8 …

The selective borylation of specific C− H bonds in organic synthesis remains a formidable
challenge. In this study, we present a novel spirobipyridine ligand that features a binaphthyl …

Combined computational and experimental studies elucidate the mechanism and suggest
rational design and optimization strategies of a bis (phosphine)-supported iridium-catalyst …

Density functional theory calculations were performed to investigate the iridium-catalyzed
intramolecular silylation of unactivated C (sp3)–H bonds. The computations show that the in …