Cleavage of Si–H, B–H, and C–H bonds by metal–ligand cooperation: focus review
T Higashi, S Kusumoto, K Nozaki - Chemical reviews, 2019 - ACS Publications
Metal–ligand cooperation, in which metal and ligand participate in bond cleavage and
formation, is gathering great attention in recent years. In contrast to the classical bond …
formation, is gathering great attention in recent years. In contrast to the classical bond …
1, 3-N, O-Complexes of late transition metals. Ligands with flexible bonding modes and reaction profiles
1, 3-N, O-Chelating ligands are ubiquitous in nature owing to their occurrence as α-chiral
amino acids in metalloproteins. These structural units also display diverse coordination …
amino acids in metalloproteins. These structural units also display diverse coordination …
Stronger Together! Mechanistic investigation into synergistic effects during homogeneous carbon dioxide hydrogenation using a heterobimetallic catalyst
ZBG Fickenscher, P Lönnecke, AK Müller… - Inorganic …, 2023 - ACS Publications
A series of group 6 heterobimetallic complexes [M0; IrIII](M= Cr, Mo, W) were synthesized
and fully characterized, and the catalytic behavior was studied. The heterobimetallic …
and fully characterized, and the catalytic behavior was studied. The heterobimetallic …
Capturing HBCy2: Using N,O‐Chelated Complexes of Rhodium(I) and Iridium(I) for Chemoselective Hydroboration
N, O‐chelated complexes of RhI and IrI cooperatively and reversibly stabilized the B− H
bond of HBCy2 to afford six‐membered metallaheterocycles (M= Rh (7) or Ir (8)) having a δ …
bond of HBCy2 to afford six‐membered metallaheterocycles (M= Rh (7) or Ir (8)) having a δ …
Cooperative B–H and Si–H Bond Activations by κ2-N,S-Chelated Ruthenium Borate Complexes
Cooperative E–H (E= B, Si) bond activations employing κ2-N, S-chelated ruthenium borate
species,[PPh3 {κ2-N, S-(NS2C7H4)} Ru {κ3-H, S, S′-H2B (NC7H4S2) 2}],(1) are …
species,[PPh3 {κ2-N, S-(NS2C7H4)} Ru {κ3-H, S, S′-H2B (NC7H4S2) 2}],(1) are …
Oxidation State Dependent Coordination Modes: Accessing an Amidate‐Supported Nickel (I) δ‐bis (C− H) Agostic Complex
Amidate‐supported two‐and three‐coordinate NiI complexes were synthesized by reduction
of the corresponding NiII precursors. A dramatic change in binding mode is observed upon …
of the corresponding NiII precursors. A dramatic change in binding mode is observed upon …
Ligand Postsynthetic Functionalization with Fluorinated Boranes and Implications in Hydrogenation Catalysis
The incorporation of boron functionalities into transition-metal catalysts has become a
promising strategy to improve catalytic performance, although their synthesis typically entails …
promising strategy to improve catalytic performance, although their synthesis typically entails …
Effect of the ortho‐Hydroxyl Groups on a Bipyridine Ligand of Iridium Complexes for the High‐Pressure Gas Generation from the Catalytic Decomposition of Formic …
The hydroxyl groups of a 2, 2′‐bipyridine (bpy) ligand near the metal center activated the
catalytic performance of the Ir complex for the dehydrogenation of formic acid at high …
catalytic performance of the Ir complex for the dehydrogenation of formic acid at high …
Toward anti-Markovnikov 1-Alkyne O-Phosphoramidation: Exploiting Metal–Ligand Cooperativity in a 1,3-N,O-Chelated Cp*Ir(III) Complex
Metal–ligand cooperation between iridium (III) and a 1, 3-N, O-chelating phosphoramidate
ligand has been used to develop a protocol for the intermolecular O-phosphoramidation of 1 …
ligand has been used to develop a protocol for the intermolecular O-phosphoramidation of 1 …
Umpolung of B− H Bonds by Metal–Ligand Cooperation with Cyclopentadienone Iridium Complexes
T Higashi, S Kusumoto, K Nozaki - Angewandte Chemie, 2021 - Wiley Online Library
In contrast to conventional metal–ligand cooperative cleavage of a B− H bond, which
provides a B cation on the ligand and an H anion on the metal, we report herein the …
provides a B cation on the ligand and an H anion on the metal, we report herein the …