Strategies for binding multiple guests in metal–organic cages
The binding of multiple guests by a single entity can lead to new modes of host–guest
interactions and thus new applications in, for example, catalysis and sensing. With the aim of …
interactions and thus new applications in, for example, catalysis and sensing. With the aim of …
Strategies for reversible guest uptake and release from metallosupramolecular architectures
TY Kim, RAS Vasdev, D Preston… - Chemistry–A European …, 2018 - Wiley Online Library
The cavities of metallosupramolecular cages can be used to mimic the central spaces of
naturally occurring proteins and bind a wide variety of molecular guests. A range of potential …
naturally occurring proteins and bind a wide variety of molecular guests. A range of potential …
Molecular confinement effects by self-assembled coordination cages
H Takezawa, M Fujita - Bulletin of the Chemical Society of …, 2021 - academic.oup.com
When substrates are confined in an isolated cavity, they experience circumstances that are
distinctly different from those in a bulk solution. Molecular self-assembly has widened the …
distinctly different from those in a bulk solution. Molecular self-assembly has widened the …
Combinatorial Self‐Assembly of Coordination Cages with Systematically Fine‐Tuned Cavities for Efficient Co‐Encapsulation and Catalysis
SC Li, LX Cai, M Hong, Q Chen… - Angewandte Chemie …, 2022 - Wiley Online Library
Controllable arrangement of different ligands in a single assembly will not only bring
increased complexity but also offers a new route to fine‐tune the function of the designed …
increased complexity but also offers a new route to fine‐tune the function of the designed …
Coordination-driven self-assembled metallacycles incorporating pyrene: fluorescence mutability, tunability, and aromatic amine sensing
Constructing polycyclic aromatics-based, highly emissive fluorophores with good solubility
and tunable aggregated structures and properties is of great importance for film fabrication …
and tunable aggregated structures and properties is of great importance for film fabrication …
Separation and Selective Formation of Fullerene Adducts within an MII8L6 Cage
W Brenner, TK Ronson, JR Nitschke - Journal of the American …, 2017 - ACS Publications
The self-assembly of 4-fold-symmetric porphyrins with FeII or ZnII gave a new cubic MII8L6
cage framework with electron-deficient walls. This cage bound C60-indene or C60 …
cage framework with electron-deficient walls. This cage bound C60-indene or C60 …
Multicavity [PdnL4]2n+ Cages with Controlled Segregated Binding of Different Guests
Multicavity [Pd n (L) 4] 2 n+ metallosupramolecular cages based on long backboned ligands
are an attractive approach to increasing molecular size without loss of the binding specificity …
are an attractive approach to increasing molecular size without loss of the binding specificity …
Selective Confinement of Rare‐Earth‐Metal Hydrates by a Capped Metallo‐Cage under Aqueous Conditions
R Tabuchi, H Takezawa, M Fujita - Angewandte Chemie, 2022 - Wiley Online Library
The properties of rare‐earth‐metal ions in aqueous media often depend on their various
hydration modes, which allow them to exist as monomeric or oligomeric species with …
hydration modes, which allow them to exist as monomeric or oligomeric species with …
Metal-organic materials with triazine-based ligands: From structures to properties and applications
Triazine-based ligands, featuring C 3-symmetry configuration, electron-deficient and other
triazine moiety determined characteristics, have facilitated the construction of a diverse set of …
triazine moiety determined characteristics, have facilitated the construction of a diverse set of …
Unexpected Macrocyclic Multinuclear Zinc and Nickel Complexes that Function as Multitasking Catalysts for CO2 Fixations
K Takaishi, BD Nath, Y Yamada, H Kosugi… - Angewandte …, 2019 - Wiley Online Library
Unique self‐assembled macrocyclic multinuclear ZnII and NiII complexes with binaphthyl‐
bipyridyl ligands (L) were synthesized. X‐ray analysis revealed that these complexes …
bipyridyl ligands (L) were synthesized. X‐ray analysis revealed that these complexes …