Metal complexes containing redox-active ligands in oxidation of hydrocarbons and alcohols: A review
GB Shul'pin, YN Kozlov, LS Shul'pina - Catalysts, 2019 - mdpi.com
Ligands are innocent when they allow oxidation states of the central atoms to be defined. A
noninnocent (or redox) ligand is a ligand in a metal complex where the oxidation state is not …
noninnocent (or redox) ligand is a ligand in a metal complex where the oxidation state is not …
Oxidation of organic compounds with peroxides catalyzed by polynuclear metal compounds
GB Shul'pin, LS Shul'pina - Catalysts, 2021 - mdpi.com
The review describes articles that provide data on the synthesis and study of the properties
of catalysts for the oxidation of alkanes, olefins, and alcohols. These catalysts are …
of catalysts for the oxidation of alkanes, olefins, and alcohols. These catalysts are …
Acetone Factor in the Design of Cu4-, Cu6-, and Cu9-Based Cage Coppersilsesquioxanes: Synthesis, Structural Features, and Catalytic Functionalization of …
AN Bilyachenko, EI Gutsul, VN Khrustalev… - Inorganic …, 2022 - ACS Publications
The present study describes a new feature in the self-assembly of cagelike
copperphenylsilsesquioxanes: the strong influence of acetone solvates on cage structure …
copperphenylsilsesquioxanes: the strong influence of acetone solvates on cage structure …
Exploring Cagelike Silsesquioxane Building Blocks for the Design of Heterometallic Cu4/M4 Architectures
Within the sweeping research on the design of new coordination polymers and related metal–
organic architectures, the use of silsesquioxane derivatives as important organosilicon …
organic architectures, the use of silsesquioxane derivatives as important organosilicon …
Cagelike Manganesesilsesquioxane Complexes: Synthesis via an Acetone Approach, Structure, and Catalytic Activity for Toluene Oxidation
AN Bilyachenko, EI Gutsul, VN Khrustalev… - Crystal Growth & …, 2023 - ACS Publications
The study describes a new feature in the self-assembly of cagelike manganese-based
phenylsilsesquioxanes consisting of the strong influence of acetone solvates on the …
phenylsilsesquioxanes consisting of the strong influence of acetone solvates on the …
Hybrid Silsesquioxane/Benzoate Cu7-Complexes: Synthesis, Unique Cage Structure, and Catalytic Activity
A series of phenylsilsesquioxane-benzoate heptacopper complexes 1–3 were synthesized
and characterized by X-ray crystallography. Two parallel routes of toluene spontaneous …
and characterized by X-ray crystallography. Two parallel routes of toluene spontaneous …
Cu6- and Cu8-Cage Sil- and Germsesquioxanes: Synthetic and Structural Features, Oxidative Rearrangements, and Catalytic Activity
This study reports intriguing features in the self-assembly of cage copper (II) silsesquioxanes
in the presence of air. Despite the wide variation of solvates used, a series of prismatic …
in the presence of air. Despite the wide variation of solvates used, a series of prismatic …
The sensitive detection and mechanism of Fe-3, 5-dimethyl pyrazole fluorescent sensor to diethylenetriamine pentamethylene phosphonic acid: Experimental study …
Diethylenetriamine pentamethylene phosphonic acid (DTPMP) is one of the most commonly
used amino organic phosphonates. The existing methods for DTPMP detection are …
used amino organic phosphonates. The existing methods for DTPMP detection are …
Selective peroxidative conversion of ethylbenzene catalyzed by Mn (II) complex under solvent-free conditions
Z Razmara, F Razmara, S Shahraki - Inorganic Chemistry Communications, 2024 - Elsevier
An inorganic complex of Mn (II) formulated as [Mn (pzo) 2 (H 2 O) 2] where pzo= Pyrazonic
acid has been synthesized using two different methods; under ultrasonic irradiation as …
acid has been synthesized using two different methods; under ultrasonic irradiation as …
Rational (supra) molecular design and catalytic activity of cage-like Cu 4-based phenylsilsesquioxanes
An extended (ie, 19 distinct species) family of cage-like Cu4-phenylsilsesquioxanes allowed
us to accentuate the general regularities behind their structural organization. Influencing …
us to accentuate the general regularities behind their structural organization. Influencing …