Energy transfer photocatalysis: exciting modes of reactivity
Excited (triplet) states offer a myriad of attractive synthetic pathways, including
cycloadditions, selective homolytic bond cleavages and strain-release chemistry …
cycloadditions, selective homolytic bond cleavages and strain-release chemistry …
Enantioselective radical reactions using chiral catalysts
Benefiting from the impressive increase in fundamental knowledge, the last 20 years have
shown a continuous burst of new ideas and consequently a plethora of new catalytic …
shown a continuous burst of new ideas and consequently a plethora of new catalytic …
Photons or electrons? A critical comparison of electrochemistry and photoredox catalysis for organic synthesis
NES Tay, D Lehnherr, T Rovis - Chemical reviews, 2021 - ACS Publications
Redox processes are at the heart of synthetic methods that rely on either electrochemistry or
photoredox catalysis, but how do electrochemistry and photoredox catalysis compare? Both …
photoredox catalysis, but how do electrochemistry and photoredox catalysis compare? Both …
Chiral photocatalyst structures in asymmetric photochemical synthesis
Asymmetric catalysis is a major theme of research in contemporary synthetic organic
chemistry. The discovery of general strategies for highly enantioselective photochemical …
chemistry. The discovery of general strategies for highly enantioselective photochemical …
Enantioselective photochemical reactions enabled by triplet energy transfer
J Großkopf, T Kratz, T Rigotti, T Bach - Chemical Reviews, 2021 - ACS Publications
For molecules with a singlet ground state, the population of triplet states is mainly possible
(a) by direct excitation and subsequent intersystem crossing or (b) by energy transfer from …
(a) by direct excitation and subsequent intersystem crossing or (b) by energy transfer from …
Enantioselective [2+ 2]-cycloadditions with triplet photoenzymes
N Sun, J Huang, J Qian, TP Zhou, J Guo, L Tang… - Nature, 2022 - nature.com
Naturally evolved enzymes, despite their astonishingly large variety and functional diversity,
operate predominantly through thermochemical activation. Integrating prominent …
operate predominantly through thermochemical activation. Integrating prominent …
Triplet energy transfer photocatalysis: unlocking the next level
F Strieth-Kalthoff, F Glorius - Chem, 2020 - cell.com
Energy transfer can leverage the enormous potential of excited-state reactivity. Through"
indirect excitation" of substrates, otherwise elusive reactivity modes can be switched on …
indirect excitation" of substrates, otherwise elusive reactivity modes can be switched on …
New redox strategies in organic synthesis by means of electrochemistry and photochemistry
As the breadth of radical chemistry grows, new means to promote and regulate single-
electron redox activities play increasingly important roles in driving modern synthetic …
electron redox activities play increasingly important roles in driving modern synthetic …
Multiplicative enhancement of stereoenrichment by a single catalyst for deracemization of alcohols
L Wen, J Ding, L Duan, S Wang, Q An, H Wang, Z Zuo - Science, 2023 - science.org
Stereochemical enrichment of a racemic mixture by deracemization must overcome
unfavorable entropic effects as well as the principle of microscopic reversibility; recently …
unfavorable entropic effects as well as the principle of microscopic reversibility; recently …
Non-equilibrium steady states in catalysis, molecular motors, and supramolecular materials: why networks and language matter
I Aprahamian, SM Goldup - Journal of the American Chemical …, 2023 - ACS Publications
All chemists are familiar with the idea that, at equilibrium steady state, the relative
concentrations of species present in a system are predicted by the corresponding …
concentrations of species present in a system are predicted by the corresponding …