1-Adamantyl acetate (5) and 1-adamantyl silyl ether (12) react with unsaturated
organosilanes exactly as the chloride 1 does; the reactions of 5 catalyzed by trimethylsilyl …

Treatment of A-chloro-A-ethyl-l-adamantanamine (3) with aluminum chlorideafforded
rearranged product which was isolated as endo-AT-ethyl-7-aminomethylbicyclo [3.3. 1] …

Facile and almost quantitative carbonylation of primary and secondary amines was
performed at room tem-perature with a combination of carbon monoxide and silver acetate …

The solvolysis of l-chloro-3, 3-dimethyl-2-azabicyclo [2.2. 2] octane (2) was examined in
70% dioxane-water and in absolute ethanol. The sole products were 4-[2-amino-2-propyl] …

Exposure of 1-A, A-dichloroaminoapocamphane to aluminum chloride leads to the
rearrangement product, l-chloro-3, 3-dimethyl-2-azabicyclo [2.2. 2] octane (10% yield), as …

Treatment of',-dichlorotri-n-butylcarbinamine withaluminum chloride in methylene chloride,
followed by acid hydrolysis, produced di-n-butyl ketoneand n-butylaminein yields of 95 and …

The readily available e «do-7-aminomethylbicyclo [3.3. 1] nonan-3-one serves as a
convenient precursor for a variety of 3-and 3, 7-substituted bicyclo [3.3. 1] nonanes. The …

Two diastereomers of? ra/«-3, 4-dimethylcycloocta-1, 5-diene (3) can exist whichdiffer in the
axial dissymmetry element associated with the ring. In principle, they should be thermally …

IVyV-Dihalo derivatives of (1-adamantyl)-and neopentylamine are converted to the
corresponding alkyl halides in excellent yields (88-94%) during GLC at 155-330 C …

In 1971 it was reported that/V-chloro-N-acetyl-1-ami-noadamantane (1) rearranges to3-
chloro-lV-acetyl-4-azahomoadamantane (2) in carbon tetrachloride with aluminum chloride …