Electrochemical CO2 reduction (CO2RR) to multi-carbon products over copper-based catalysts

AR Woldu, Z Huang, P Zhao, L Hu, D Astruc - Coordination Chemistry …, 2022 - Elsevier
Copper has been recognized as the only heterogeneous catalyst leading to the formation of
various products of hydrocarbons and oxygenates, such as ethanol and ethylene, from the …

Spatially and temporally understanding dynamic solid–electrolyte interfaces in carbon dioxide electroreduction

J Wang, HY Tan, MY Qi, JY Li, ZR Tang… - Chemical Society …, 2023 - pubs.rsc.org
The ubiquity of solid–liquid interfaces in nature and the significant role of their atomic-scale
structure in determining interfacial properties have led to intensive research. Particularly in …

Steering the structure and selectivity of CO2 electroreduction catalysts by potential pulses

J Timoshenko, A Bergmann, C Rettenmaier, A Herzog… - Nature …, 2022 - nature.com
Convoluted selectivity trends and a missing link between reaction product distribution and
catalyst properties hinder practical applications of the electrochemical CO2 reduction …

Industrial carbon dioxide capture and utilization: state of the art and future challenges

W Gao, S Liang, R Wang, Q Jiang, Y Zhang… - Chemical Society …, 2020 - pubs.rsc.org
Dramatically increased CO2 concentration from several point sources is perceived to cause
severe greenhouse effect towards the serious ongoing global warming with associated …

Highly Selective CO2 Electroreduction to C2H4 Using a Metal–Organic Framework with Dual Active Sites

XF Qiu, HL Zhu, JR Huang, PQ Liao… - Journal of the American …, 2021 - ACS Publications
Conversion from CO2 to C2H4 is important for the development of energy and the
environment, but the high energy barrier of hydrogenation of the* CO intermediate and C–C …

In Situ Infrared Spectroscopic Evidence of Enhanced Electrochemical CO2 Reduction and C–C Coupling on Oxide-Derived Copper

EP Delmo, Y Wang, Y Song, S Zhu… - Journal of the …, 2024 - ACS Publications
The reaction mechanism of CO2 electroreduction on oxide-derived copper has not yet been
unraveled even though high C2+ Faradaic efficiencies are commonly observed on these …

Tailoring the Surface and Interface Structures of Copper‐Based Catalysts for Electrochemical Reduction of CO2 to Ethylene and Ethanol

Z Zhang, L Bian, H Tian, Y Liu, Y Bando, Y Yamauchi… - Small, 2022 - Wiley Online Library
Electrochemical CO2 reduction to valuable ethylene and ethanol offers a promising strategy
to lower CO2 emissions while storing renewable electricity. Cu‐based catalysts have shown …

In Situ/Operando Electrocatalyst Characterization by X-ray Absorption Spectroscopy

J Timoshenko, B Roldan Cuenya - Chemical reviews, 2020 - ACS Publications
During the last decades, X-ray absorption spectroscopy (XAS) has become an
indispensable method for probing the structure and composition of heterogeneous catalysts …

Modeling Operando Electrochemical CO2 Reduction

F Dattila, RR Seemakurthi, Y Zhou, N López - Chemical Reviews, 2022 - ACS Publications
Since the seminal works on the application of density functional theory and the
computational hydrogen electrode to electrochemical CO2 reduction (eCO2R) and …

Revealing the CO Coverage-Driven C–C Coupling Mechanism for Electrochemical CO2 Reduction on Cu2O Nanocubes via Operando Raman Spectroscopy

C Zhan, F Dattila, C Rettenmaier, A Bergmann… - ACS …, 2021 - ACS Publications
Electrochemical reduction of carbon dioxide (CO2RR) is an attractive route to close the
carbon cycle and potentially turn CO2 into valuable chemicals and fuels. However, the …