Selective hydrogenation over supported metal catalysts: from nanoparticles to single atoms

L Zhang, M Zhou, A Wang, T Zhang - Chemical reviews, 2019 - ACS Publications
Selective catalytic hydrogenation has wide applications in both petrochemical and fine
chemical industries, however, it remains challenging when two or multiple functional groups …

Guidelines to achieving high selectivity for the hydrogenation of α, β-unsaturated aldehydes with bimetallic and dilute alloy catalysts: a review

M Luneau, JS Lim, DA Patel, ECH Sykes… - Chemical …, 2020 - ACS Publications
Selective hydrogenation of α, β-unsaturated aldehydes to unsaturated alcohols is a
challenging class of reactions, yielding valuable intermediates for the production of …

Atomically dispersed Pd on nanodiamond/graphene hybrid for selective hydrogenation of acetylene

F Huang, Y Deng, Y Chen, X Cai, M Peng… - Journal of the …, 2018 - ACS Publications
We reported here a strategy to use a defective nanodiamond-graphene (ND@ G) to prepare
an atomically dispersed metal catalyst, ie, in the current case atomically dispersed palladium …

Nickel‐based high‐entropy intermetallic as a highly active and selective catalyst for acetylene semihydrogenation

J Ma, F Xing, Y Nakaya, K Shimizu… - Angewandte …, 2022 - Wiley Online Library
Acetylene semihydrogenation is a key technology for producing polymer‐grade ethylene
from crude ethylene. Ni‐based catalysts are promising alternatives to noble‐metals for this …

Selective ensembles in supported palladium sulfide nanoparticles for alkyne semi-hydrogenation

D Albani, M Shahrokhi, Z Chen, S Mitchell… - Nature …, 2018 - nature.com
Ensemble control has been intensively pursued for decades to identify sustainable
alternatives to the Lindlar catalyst (PdPb/CaCO3) applied for the partial hydrogenation of …

AgPd and CuPd catalysts for selective hydrogenation of acetylene

MR Ball, KR Rivera-Dones, EB Gilcher… - ACS …, 2020 - ACS Publications
The selective hydrogenation of acetylene has been studied over AgPd and CuPd catalysts.
Controlled surface reactions were used to synthesize these bimetallic nanoparticles on both …

Increasing the distance of adjacent palladium atoms for configuration matching in selective hydrogenation

X Ge, Y Cao, K Yan, Y Li, L Zhou, S Dai… - Angewandte Chemie …, 2022 - Wiley Online Library
Precisely tailoring the distance between adjacent metal sites to match adsorption
configurations of key species for the targeted reaction pathway is a great challenge in …

Decoding reactive structures in dilute alloy catalysts

N Marcella, JS Lim, AM Płonka, G Yan, CJ Owen… - Nature …, 2022 - nature.com
Rational catalyst design is crucial toward achieving more energy-efficient and sustainable
catalytic processes. Understanding and modeling catalytic reaction pathways and kinetics …

Mechanism driven design of trimer Ni1Sb2 site delivering superior hydrogenation selectivity to ethylene

X Ge, M Dou, Y Cao, X Liu, Q Yuwen, J Zhang… - Nature …, 2022 - nature.com
Mechanism driven catalyst design with atomically uniform ensemble sites is an important yet
challenging issue in heterogeneous catalysis associated with breaking the activity-selectivity …

Pd single-atom catalysts derived from strong metal-support interaction for selective hydrogenation of acetylene

Y Guo, Y Li, X Du, L Li, Q Jiang, B Qiao - Nano Research, 2022 - Springer
Selective hydrogenation of acetylene in excess ethylene is an important reaction in both
fundamental study and practical application. Pd-based catalysts with high intrinsic activity …