Selective hydrogenation over supported metal catalysts: from nanoparticles to single atoms
L Zhang, M Zhou, A Wang, T Zhang - Chemical reviews, 2019 - ACS Publications
Selective catalytic hydrogenation has wide applications in both petrochemical and fine
chemical industries, however, it remains challenging when two or multiple functional groups …
chemical industries, however, it remains challenging when two or multiple functional groups …
Guidelines to achieving high selectivity for the hydrogenation of α, β-unsaturated aldehydes with bimetallic and dilute alloy catalysts: a review
Selective hydrogenation of α, β-unsaturated aldehydes to unsaturated alcohols is a
challenging class of reactions, yielding valuable intermediates for the production of …
challenging class of reactions, yielding valuable intermediates for the production of …
Atomically dispersed Pd on nanodiamond/graphene hybrid for selective hydrogenation of acetylene
We reported here a strategy to use a defective nanodiamond-graphene (ND@ G) to prepare
an atomically dispersed metal catalyst, ie, in the current case atomically dispersed palladium …
an atomically dispersed metal catalyst, ie, in the current case atomically dispersed palladium …
Nickel‐based high‐entropy intermetallic as a highly active and selective catalyst for acetylene semihydrogenation
Acetylene semihydrogenation is a key technology for producing polymer‐grade ethylene
from crude ethylene. Ni‐based catalysts are promising alternatives to noble‐metals for this …
from crude ethylene. Ni‐based catalysts are promising alternatives to noble‐metals for this …
Selective ensembles in supported palladium sulfide nanoparticles for alkyne semi-hydrogenation
Ensemble control has been intensively pursued for decades to identify sustainable
alternatives to the Lindlar catalyst (PdPb/CaCO3) applied for the partial hydrogenation of …
alternatives to the Lindlar catalyst (PdPb/CaCO3) applied for the partial hydrogenation of …
AgPd and CuPd catalysts for selective hydrogenation of acetylene
MR Ball, KR Rivera-Dones, EB Gilcher… - ACS …, 2020 - ACS Publications
The selective hydrogenation of acetylene has been studied over AgPd and CuPd catalysts.
Controlled surface reactions were used to synthesize these bimetallic nanoparticles on both …
Controlled surface reactions were used to synthesize these bimetallic nanoparticles on both …
Increasing the distance of adjacent palladium atoms for configuration matching in selective hydrogenation
Precisely tailoring the distance between adjacent metal sites to match adsorption
configurations of key species for the targeted reaction pathway is a great challenge in …
configurations of key species for the targeted reaction pathway is a great challenge in …
Decoding reactive structures in dilute alloy catalysts
Rational catalyst design is crucial toward achieving more energy-efficient and sustainable
catalytic processes. Understanding and modeling catalytic reaction pathways and kinetics …
catalytic processes. Understanding and modeling catalytic reaction pathways and kinetics …
Mechanism driven design of trimer Ni1Sb2 site delivering superior hydrogenation selectivity to ethylene
Mechanism driven catalyst design with atomically uniform ensemble sites is an important yet
challenging issue in heterogeneous catalysis associated with breaking the activity-selectivity …
challenging issue in heterogeneous catalysis associated with breaking the activity-selectivity …
Pd single-atom catalysts derived from strong metal-support interaction for selective hydrogenation of acetylene
Y Guo, Y Li, X Du, L Li, Q Jiang, B Qiao - Nano Research, 2022 - Springer
Selective hydrogenation of acetylene in excess ethylene is an important reaction in both
fundamental study and practical application. Pd-based catalysts with high intrinsic activity …
fundamental study and practical application. Pd-based catalysts with high intrinsic activity …