We present here a review of the photochemical and electrochemical applications of multi-
site proton-coupled electron transfer (MS-PCET) in organic synthesis. MS-PCETs are redox …

The first example of visible-light-driven reductive carboarylation of styrenes with CO2 and
aryl halides in a regioselective manner has been achieved. A broad range of aryl iodides …

Arylation methods based on the generation and use of aryl radicals have been a rapidly
growing field of research in recent years and currently represent a powerful strategy for …

A strategy for the mild generation of synthetically valuable α-amino radicals from robust
tertiary amide building blocks has been developed. By combining Vaska's complex …

Radical couplings of cyanopyridine radical anions represent a valuable technology for
functionalizing pyridines, which are prevalent throughout pharmaceuticals, agrochemicals …

Pyridines and quinolines are prevalent aza-arene motifs existing in drugs and natural
products. It is of great interest to develop a more step-and atom-economy strategy for the …

A systematized survey of reviews and monographs published in 2019 on all aspects of
heterocyclic chemistry is given. Methods for the synthesis, reactivity, and practically useful …

The radical hydroarylation of alkenes is an efficient strategy for accessing linear alkylarenes
with high regioselectivity. Herein, we report the electroreductive hydroarylation of electron …

2. If any part of this thesis has been previously used for an academic degree or other
qualification at this or any other institution, this has been clearly declared. 3. Whenever other …

Nitrogen-containing heterocycles, particularly pyridines and piperidines, are important
components of many bioactive pharmaceuticals and natural products. Furthermore, it has …