Radical C–H functionalization represents a useful means of streamlining synthetic routes by
avoiding substrate preactivation and allowing access to target molecules in fewer steps. The …

Axially chiral compounds have been always considered a laboratory curiosity with rare
prospects of being applied in asymmetric synthesis. Things have changed very quickly in the …

This study establishes the first organocatalytic enantioselective synthesis of axially chiral N,
N′‐bisindoles via chiral phosphoric acid‐catalyzed formal (3+ 2) cycloadditions of indole …

Catalytic enantioselective preparation of alkene atropisomers with multiple stereogenic
elements and discovery of their applications have become significant but challenging issues …

Covering: 2008 to 2023 This review will describe oxidative phenol coupling as applied in the
total synthesis of natural products. This review covers catalytic and electrochemical methods …

In the chemistry community, catalytic asymmetric synthesis of furan‐based compounds
bearing both axial and central chirality has proven to be a significant but challenging issue …

A copper‐catalyzed atroposelective ring‐opening reaction of cyclic diaryliodoniums, sodium
cyanate (NaOCN) and phenols is reported. The reaction chemoselectively affords axially …

Chiral aluminum oxo clusters (cAlOCs) are distinguished from other classes of materials on
account of their abundance in the earth's crust and their potential for sustainable …

BINOL derivatives have shown relevant biological activities and are important chiral ligands
and catalysts. Due to these properties, their asymmetric synthesis has attracted the interest …

Optically pure BINOL (1, 1′-bi-2-naphthol) and diversely substituted BINOLs are highly
valuable chiral motifs featuring axial chirality widely applied in various fields. Although …