C–H activation has surfaced as an increasingly powerful tool for molecular sciences, with
notable applications to material sciences, crop protection, drug discovery, and …

Employing phenols and phenol derivatives as electrophiles for cross-coupling reactions has
numerous advantages over commonly used aryl halides in terms of environmental …

Catalytic cross-coupling reactions of aromatic esters and amides have recently gained
considerable attention from synthetic chemists as de novo and efficient synthetic methods to …

The field of organometallic catalysis has attracted considerable interest from both academia
and industry due to its broad applications in synthetic transformations. Pd, Ni, Rh, and Ir …

In this Tutorial Review, we make the point that a true understanding of trends in reactivity (as
opposed to measuring or simply computing them) requires a causal reactivity model. To this …

Metal-catalyzed cross-couplings represent one of the most important reaction platforms in
modern synthetic chemistry (Figure 1 A). 1 Although the field enjoys a rich history, there …

Linear scaling relationships between the adsorption energies of CO2 reduction
intermediates pose a fundamental limitation to the catalytic efficiency of transition-metal …

The Suzuki–Miyaura coupling is among the most important C–C bond-forming reactions
available due to its reliability, chemoselectivity, and diversity. Aryl halides and …

A catalytic protocol to convert aryl and heteroaryl chlorides to the corresponding
trifluoromethyl sulfides is reported herein. It relies on a relatively inexpensive Ni (cod) 2/dppf …

Abstract The Suzuki–Miyaura cross-coupling is a metal-catalysed reaction in which boron-
based nucleophiles and halide-based electrophiles are reacted to form a single molecule …