Visible-light-induced cascade reaction: a sustainable approach towards molecular complexity
Photoredox catalysis has demonstrated rapid evolution in the field of synthetic organic
chemistry. On the other hand, the splendour of cascade reactions in providing complex …
chemistry. On the other hand, the splendour of cascade reactions in providing complex …
[RhCp*Cl2]2-Catalyzed Indole Functionalization: Synthesis of Bioinspired Indole-Fused Polycycles
AN Singh Chauhan, G Mali, G Dua, P Samant… - ACS …, 2023 - ACS Publications
Polycyclic fused indoles are ubiquitous in natural products and pharmaceuticals due to their
immense structural diversity and biological inference, making them suitable for charting …
immense structural diversity and biological inference, making them suitable for charting …
Catalytic Asymmetric Polycyclization of Tertiary Enamides with Silyl Enol Ethers: Total Synthesis of (−)-Cephalocyclidin A
QB Zhuang, JR Tian, K Lu, XM Zhang… - Journal of the …, 2023 - ACS Publications
A catalytic enantioselective polycyclization of tertiary enamides with terminal silyl enol ethers
has been developed by virtue of Cu (OTf) 2 catalysis with a novel spiropyrroline-derived …
has been developed by virtue of Cu (OTf) 2 catalysis with a novel spiropyrroline-derived …
Photochemical Intermolecular Cyclopropanation Reactions of Allylic Alcohols for the Synthesis of [3.1. 0]-Bicyclohexanes
Cyclopropane-fused lactones are highly desirable in drug and natural products synthesis.
Herein, we report on a photochemical, chemoselective reaction of aryldiazoacetates with …
Herein, we report on a photochemical, chemoselective reaction of aryldiazoacetates with …
Dipole‐Transmissive 1, 3‐Dipolar Cycloadditions for the Rapid Construction of Polycyclic N‐Heterocycles: Synthetic and Mechanistic Investigations
JS Henneveld, F Shiri, A Ariafard… - … A European Journal, 2023 - Wiley Online Library
The investigation of distinctive dipole‐transmissive dipolar cycloaddition (DTDC)
methodology and the formalisation of this concept is reported. A DTDC procedure was able …
methodology and the formalisation of this concept is reported. A DTDC procedure was able …
Mn‐Mediated Radical Cascade Cyclization of 1,6‐Enynes with Arylboronic Acids to Access Dihydrobenzo[b]fluorenones
C Raji Reddy, R Chandrakant Kajare… - Advanced Synthesis & …, 2022 - Wiley Online Library
Herein, we report the synthesis of functionalized dihydro‐benzo [b] fluorenones through a
manganese‐mediated cascade radical cyclization of β‐alkynyl propenones [1, 6‐enynes] …
manganese‐mediated cascade radical cyclization of β‐alkynyl propenones [1, 6‐enynes] …
Substitution controlled aryne insertion: synthesis of diarylmethane/chromones
JR Dhanaji, P Samatha, S Raju, PS Mainkar… - Chemical …, 2023 - pubs.rsc.org
Aryne insertion reaction with 2-aroyl malonates/cyanoesters lead to the formation of
diarylmethane or chromones depending on the substitution on the aryne ring. The presence …
diarylmethane or chromones depending on the substitution on the aryne ring. The presence …
Recent Advances in [3+ 2]-Cycloaddition-Enabled Cascade Reactions: Application to Synthesize Complex Organic Frameworks
Many natural products and biologically important complex organic scaffolds have
convoluted structures around their core skeleton. Interestingly, with just changing the …
convoluted structures around their core skeleton. Interestingly, with just changing the …
Catalyst-Controlled Inter-and Intramolecular Cascade [4+ 2] Annulations via Benzopyrylium Intermediates
We report two types of catalyst-controlled inter-and intramolecular cascade [4+ 2]
annulations between diyne-carbonyls and alkenes, Pt (II)-catalyzed annulation with two …
annulations between diyne-carbonyls and alkenes, Pt (II)-catalyzed annulation with two …
Total Synthesis of Strigolactones via Palladium-Catalyzed Cascade Carbonylative Carbocyclization of Enallenes
B Yang, P Federmann, V Warth, M Ren, X Mu… - Organic …, 2024 - ACS Publications
Here we report an efficient route for synthesizing strigolactones (SLs) and their derivatives.
Our method relies on a palladium-catalyzed oxidative carbonylation/carbocyclization …
Our method relies on a palladium-catalyzed oxidative carbonylation/carbocyclization …