Li self-diffusion and ion conductivity in congruent and single crystals

C Kofahl, L Dörrer, B Muscutt, S Sanna, S Hurskyy… - Physical Review …, 2023 - APS
Lithium niobate and lithium tantalate crystals are technologically important metal oxides with
exceptional combinations of ferroelectric, piezoelectric, acoustic, optical, and electrical …

Charge transport and acoustic loss in lithium niobate-lithium tantalate solid solutions at temperatures up to 900° C

U Yakhnevych, C Kofahl, S Hurskyy, S Ganschow… - Solid State Ionics, 2023 - Elsevier
Polar oxides, in particular solid solutions of lithium niobate and lithium tantalate (LNT, LiNb 1-
x Ta x O 3) are a variable model system to study fundamental materials properties due to …

Lithium-Ion Diffusion in Near-Stoichiometric Polycrystalline and Monocrystalline LiCoO2

D Uxa, E Hüger, K Meyer, L Dörrer… - Chemistry of …, 2023 - ACS Publications
Lithium-metal-oxide-based cathode materials like LiCoO2 are an essential part of lithium-ion
batteries, which are intensively researched and continuously improved. For a basic …

Hydrogen Diffusion in Li(Nb,Ta)O3 Single Crystals Probed by Infrared Spectroscopy and Secondary Ion Mass Spectrometry

C Kofahl, L Dörrer, H Wulfmeier, H Fritze… - Chemistry of …, 2024 - ACS Publications
Hydrogen is an impurity that is incorporated into LiNb1–x Ta x O3 crystals during crystal
growth or during thermal treatment in a humid atmosphere and may influence the physical …

Tracer diffusion coefficients of Li+ ions in c-axis oriented Li x CoO 2 thin films measured by secondary ion mass spectrometry

G Hasegawa, N Kuwata, Y Tanaka… - Physical Chemistry …, 2021 - pubs.rsc.org
Lithium diffusion is a key factor in determining the charge/discharge rate of Li-ion batteries.
Herein, we study the tracer diffusion coefficient (D*) of lithium ions in the c-axis oriented …

Spontaneous polarization and pyroelectric coefficient of lithium niobate and lithium tantalate determined from crystal structure data

T Weigel, C Ludt, T Leisegang, E Mehner, S Jachalke… - Physical review B, 2023 - APS
This work shows an alternative approach to extract the pyroelectric coefficient directly from
the response of the crystal structure to temperature variations. The approach uses crystal …

High-temperature electrical conductivity in piezoelectric lithium niobate

K Lucas, S Bouchy, P Bélanger… - Journal of Applied Physics, 2022 - pubs.aip.org
Lithium niobate is a promising candidate for use in high-temperature piezoelectric devices
due to its high Curie temperature (⁠≈ 1483 K) and strong piezoelectric properties …

Experimental determination of Li diffusivity in LLZO using isotopic exchange and FIB-SIMS

RH Brugge, RJ Chater, JA Kilner… - Journal of Physics …, 2021 - iopscience.iop.org
Current lithium ion battery technology makes use of flammable liquid electrolytes and so the
development of solid ceramic electrolytes for the next generation of all-solid-state batteries …

On the Active Components in Crystalline Li–Nb–O and Li–Ta–O Coatings from First Principles

H Chen, Z Deng, Y Li, P Canepa - Chemistry of Materials, 2023 - ACS Publications
Layered-oxide LiNi x Mn y Co1–x–y O2 (NMC) positive electrodes with high nickel content
deliver high voltages and energy densities. However, a high nickel content, eg, x= 0.8 …

[HTML][HTML] Lithium diffusion coefficient in amorphous lithium phosphate thin films measured by secondary ion mass spectroscopy with isotope exchange methods

N Kuwata, X Lu, T Miyazaki, Y Iwai, T Tanabe… - Solid State Ionics, 2016 - Elsevier
Lithium diffusion coefficients in amorphous lithium phosphate (a-Li 3 PO 4) thin films were
determined by secondary ion mass spectroscopy (SIMS), using 7 Li and 6 Li stable isotopes …