Two-coordinate thermally activated delayed fluorescence coinage metal complexes: Molecular design, photophysical characters, and device application

TY Li, SJ Zheng, PI Djurovich, ME Thompson - Chemical Reviews, 2024 - ACS Publications
Since the emergence of the first green light emission from a fluorescent thin-film organic light
emitting diode (OLED) in the mid-1980s, a global consumer market for OLED displays has …

Intersystem crossing, phosphorescence, and spin-orbit coupling. Two contrasting Cu (I)-TADF dimers investigated by milli-to micro-second phosphorescence, femto …

H Yersin, R Czerwieniec, U Monkowius… - Coordination Chemistry …, 2023 - Elsevier
Applying femto-second time-resolved spectroscopy, we study intersystem crossing times τ
(ISC) of two Cu (I) dimers, Cu 2 Cl 2 (dppb) 2 1 (dppb= 1, 2-bis-diphenylphosphino) …

Cu (I) and Ag (I) complexes with a new type of rigid tridentate N, P, P-ligand for thermally activated delayed fluorescence and OLEDs with high external quantum …

M Klein, N Rau, M Wende, J Sundermeyer… - Chemistry of …, 2020 - ACS Publications
Neutral Cu (I) and Ag (I) complexes with a new rigid tridentate N, P, P ligand (dmpzpp, 3, 5-
dimethyl-1-(2-((2-(di-o-tolyl) phosphanyl)(o-tolyl)-phosphanyl) phenyl)-1 H-pyrazole), giving …

Thermally activated delayed fluorescence materials for organic light-emitting diodes

X Li, S Fu, Y Xie, Z Li - Reports on Progress in Physics, 2023 - iopscience.iop.org
Recently, the remarkable advances in thermally activated delayed fluorescence (TADF)
materials have attracted much attention due to their 100% exciton utilization efficiency in …

Crystalline metal‐organic materials with thermally activated delayed fluorescence

Z Han, XY Dong, SQ Zang - Advanced Optical Materials, 2021 - Wiley Online Library
Thermally activated delayed fluorescence (TADF) properties of crystalline metal‐organic
materials, mainly including small‐molecule metal–organic complexes, organic ligand …

Ln3+ Induced Thermally Activated Delayed Fluorescence of Chiral Heterometallic Clusters Ln2Ag28

XT Wang, SR He, FW Lv, XT Wang… - Angewandte Chemie …, 2024 - Wiley Online Library
A series of TADF‐active compounds: 0D chiral Ln− Ag (I) clusters L‐/D‐Ln2Ag28‐0D (Ln=
Eu/Gd) and 2D chiral Ln− Ag (I) cluster‐based frameworks L‐/D‐Ln2Ag28‐2D (Ln= Gd) has …

Three silver (I) coordination polymers based on pyridyl ligands and auxiliary carboxylic ligands: luminescence and efficient sensing properties

CC Chen, Y Cai, LF Wang, YD Wu, HJ Yin… - Inorganic …, 2021 - ACS Publications
Easily producible sensors for harmful industrial waste compounds are of significant interest
for both human health and the environment. Three novel coordination polymers,[Ag (μ …

Keep it tight: a crucial role of bridging phosphine ligands in the design and optical properties of multinuclear coinage metal complexes

AV Paderina, IO Koshevoy, EV Grachova - Dalton Transactions, 2021 - pubs.rsc.org
Copper subgroup metal ions in the+ 1 oxidation state are classical candidates for
aggregation via non-covalent metal–metal interactions, which are supported by a number of …

Symmetry-based design strategy for unprecedentedly fast decaying thermally activated delayed fluorescence (TADF). Application to dinuclear Cu (I) compounds

A Schinabeck, J Chen, L Kang, T Teng… - Chemistry of …, 2019 - ACS Publications
Inspired by molecular crystal theory of coupling symmetry-related transition dipole moments,
we develop a model for rational design of Cu (I) complexes to achieve short TADF (thermally …

Sky-blue thermally activated delayed fluorescence (TADF) based on Ag (I) complexes: Strong solvation-induced emission enhancement

AV Artem'ev, MZ Shafikov, A Schinabeck… - Inorganic Chemistry …, 2019 - pubs.rsc.org
A new Ag (I) complex based on tris (2-pyridyl) phosphine (Py3P),[Ag2 (Py3P) 3 (SCN) 2],
has been synthesized and chemically characterized. Theoretical calculations and …