Single‐molecule magnets based on lanthanides are very attractive due to their potential
applications proposed in the area of microelectronic devices. Very recent advances in this …

The electronic structure of a chiral Yb (III)-based complex is fully determined by taking
advantage of experimental magnetic, luminescence, and chiroptical (NIR-ECD and CPL) …

Natural transition orbitals (NTOs) are in widespread use for visualizing and analyzing
electronic transitions. The present work introduces the analysis of formally spin-forbidden …

INTRODUCTION Developing the chemistry of late actinides is hindered by the lack of
availability of isotopes, the need for specialized research facilities, and the nuclear instability …

The electronic structures of 4f3/5f3 Cp′′ 3M and Cp′′ 3M· alkylisocyanide complexes,
where Cp′′ is 1, 3-bis-(trimethylsilyl) cyclopentadienyl, are explored with a focus on the …

Taking advantage of the steric hindrance and charge‐driving effects, four air‐stable
pentagonal bipyramidal mononuclear DyIII compounds were hydrothermally synthesized …

Divalent lanthanide organometallics are well‐known highly reducing compounds usually
used for single electron transfer reactivity and small molecule activation. Thus, their very …

Two macrocyclic complexes of 1, 4, 7-triazacyclononane (TACN), one with N-methyl
imidazole pendants,[Fe (Mim)] 3+, and one with unsubstituted NH imidazole pendants,[Fe …

The synthesis, structural and photophysical characterization, and theoretical studies on
homo/heteroleptic neutral 2D-layered coordination polymers (CPs), obtained by combining …

Lanthanide metal–organic frameworks (Ln-MOFs) showing single-molecule magnet (SMM)
properties are an ever-growing family of materials where the magnetic properties can be …