Approach to Fully Substituted Cyclic Nitrones from N‐Hydroxylactam Derivatives: Development and Application to the Total Synthesis of Cylindricine C
S Hiraoka, T Matsumoto, K Matsuzaka… - Angewandte Chemie …, 2019 - Wiley Online Library
An approach to cyclic nitrones from N‐hydroxylactam derivatives is documented. The
nucleophilic addition of an organolithium reagent to an N‐OSEM [SEM= 2‐(trimethylsilyl) …
nucleophilic addition of an organolithium reagent to an N‐OSEM [SEM= 2‐(trimethylsilyl) …
Speciation and kinetics of fluoride transfer from tetra-n-butylammonium difluorotriphenylsilicate ('TBAT')
Tetra-n-butylammonium difluorotriphenylsilicate (TBAT) is a conveniently handled
anhydrous fluoride source, commonly used as a surrogate for tetra-n-butylammonium …
anhydrous fluoride source, commonly used as a surrogate for tetra-n-butylammonium …
Catalytic Asymmetric Synthesis of the Pentacyclic Core of (+)-Citrinadin A
The synthesis of the pentacylic core of (+)-citrinadin A is described. Our strategy harnesses
the power of palladium-catalyzed trimethylenemethane chemistry (Pd-TMM) to form the key …
the power of palladium-catalyzed trimethylenemethane chemistry (Pd-TMM) to form the key …
Magnetisation transfer NMR spectroscopy in a kinetic and mechanistic study of fluoride transfer from tetra-n-butylammonium difluorotriphenylsilicate (TBAT)
MM Kucharski - 2023 - era.ed.ac.uk
Tetra-n-butylammonium difluorotriphenylsilicate (ⁿBu₄NPh₃SiF₂, known as TBAT) is a
pentacoordinate silicon-based fluoride source, commonly used in nucleophilic fluorinations …
pentacoordinate silicon-based fluoride source, commonly used in nucleophilic fluorinations …
Total synthesis of (±)-hippolachnin A and progress toward the total synthesis of (±)-citrinadin A.
ME McCallum - 2016 - tdl-ir.tdl.org
In 2005, Kobayashi and coworkers reported the isolation and characterization of the alkaloid
natural product citrinadin A from the marine fungus Penicillium citrinum. Citrinadin A was …
natural product citrinadin A from the marine fungus Penicillium citrinum. Citrinadin A was …
[引用][C] Tetrabutylammonium Difluorotriphenylsilicate (TBAT)
NS Simpkins, FE Nytko III, P DeShong… - … of Reagents for …, 2001 - Wiley Online Library
Abstract [163931‐61‐1] C34H51NSiF2 (MW 539.88) InChI= 1/C18H15F2Si. C16H36N/c19‐
21 (20, 16‐10‐4‐1‐5‐11‐16, 17‐12‐6‐2‐7‐13‐17) 18‐14‐8‐3‐9‐15‐18; 1‐5‐9‐13‐17 (14 …
21 (20, 16‐10‐4‐1‐5‐11‐16, 17‐12‐6‐2‐7‐13‐17) 18‐14‐8‐3‐9‐15‐18; 1‐5‐9‐13‐17 (14 …