Recent advances in transition metal-catalyzed heteroannulative difunctionalization of alkenes via C–H activation for the synthesis of heterocycles
J Liu, X Xiao, Y Lai, Z Zhang - Organic Chemistry Frontiers, 2022 - pubs.rsc.org
Heterocyclic compounds are the fundamental structural motifs distributed in natural
products, pharmaceuticals and biologically active compounds. Thus, there is increasing …
products, pharmaceuticals and biologically active compounds. Thus, there is increasing …
Recent progress in rhodium-catalyzed hydroaminomethylation
C Chen, XQ Dong, X Zhang - Organic Chemistry Frontiers, 2016 - pubs.rsc.org
Hydroaminomethylation is a perfect reaction for converting alkenes into valuable amines
with high atom economy in the presence of the syngas and amines. Significant progress has …
with high atom economy in the presence of the syngas and amines. Significant progress has …
From wood to tetrahydro-2-benzazepines in three waste-free steps: modular synthesis of biologically active lignin-derived scaffolds
S Elangovan, A Afanasenko, J Haupenthal… - ACS central …, 2019 - ACS Publications
Inherently complex, lignin-derived aromatic monomers comprising valuable structural
moieties present in many pharmaceuticals would serve as ideal substrates for the …
moieties present in many pharmaceuticals would serve as ideal substrates for the …
Iridium-Catalyzed Allylic Vinylation and Asymmetric Allylic Amination Reactions with o-Aminostyrenes
An Ir-catalyzed allylic vinylation reaction of allyl carbonates with o-aminostyrene derivatives
has been realized, providing skipped (Z, E)-diene derivatives. With (E)-but-2-ene-1, 4-diyl …
has been realized, providing skipped (Z, E)-diene derivatives. With (E)-but-2-ene-1, 4-diyl …
Synthesis of Ring-Fused 1-Benzazepines via [1, 5]-Hydride Shift/7-Endo Cyclization Sequences
CW Suh, SJ Kwon, DY Kim - Organic letters, 2017 - ACS Publications
Synthesis of 1-benzazepines has been achieved via a [1, 5]-hydride shift/7-endo cyclization
sequence. The focus of this research is a direct transformation of 2-(aryl) cyclopropane 1, 1 …
sequence. The focus of this research is a direct transformation of 2-(aryl) cyclopropane 1, 1 …
Palladium-Catalyzed Oxidative Cycloaddition through C H/N H Activation: Access to Benzazepines.
L Wang, J Huang, S Peng, H Liu… - Angewandte Chemie …, 2013 - search.ebscohost.com
PalladiumCatalyzed Oxidative Cycloaddition through CH/NH Activation: Access to
Benzazepines Page 1 Benzazepine Synthesis DOI: 10.1002/anie.201208076 Palladium-Catalyzed …
Benzazepines Page 1 Benzazepine Synthesis DOI: 10.1002/anie.201208076 Palladium-Catalyzed …
Palladium-Catalyzed Dual Coupling Reaction of 2-Iodobiphenyls with o-Bromoanilines through C–H Activation: An Approach for the Synthesis of Tribenzo[b,d,f] …
C Cheng, D Tu, X Zuo, Z Wu, B Wan, Y Zhang - Organic Letters, 2021 - ACS Publications
A novel and straightforward approach for the synthesis of tribenzo [b, d, f] azepines starting
from 2-iodobiphenyls and 2-bromoanilines has been developed. A wide range of tribenzo [b …
from 2-iodobiphenyls and 2-bromoanilines has been developed. A wide range of tribenzo [b …
Enantioselective Synthesis of 2,3‐Dihydro‐1H‐benzo[b]azepines: Iridium‐Catalyzed Tandem Allylic Vinylation/Amination Reaction
H He, WB Liu, LX Dai, SL You - Angewandte Chemie International Edition, 2010 - infona.pl
Making azacycles: The [{Ir (cod) Cl} 2]/L complex efficiently catalyzes the tandem allylic
vinylation and asymmetric allylic amination of (E)‐2 with ortho‐amino styrene derivatives 1 …
vinylation and asymmetric allylic amination of (E)‐2 with ortho‐amino styrene derivatives 1 …
Enantioselective synthesis of pyrrolidine-, Piperidine-, and azepane-type N-heterocycles with α-alkenyl substitution: the CpRu-catalyzed dehydrative intramolecular N …
T Seki, S Tanaka, M Kitamura - Organic letters, 2012 - ACS Publications
A cationic CpRu complex of chiral picolinic acid derivatives [(R)-or (S)-Cl-Naph-
PyCOOCH2CH CH2] catalyzes asymmetric intramolecular dehydrative N-allylation of N …
PyCOOCH2CH CH2] catalyzes asymmetric intramolecular dehydrative N-allylation of N …
Efficient synthesis of functionalized dihydroquinolines, quinolines and dihydrobenzo [b] azepine via an iron (III) chloride-catalyzed intramolecular alkyne–carbonyl …
S Jalal, K Bera, S Sarkar, K Paul, U Jana - Organic & Biomolecular …, 2014 - pubs.rsc.org
In this study we have developed an efficient synthesis of 1, 2-dihydroquinoline and
dihydrobenzo [b] azepine derivatives involving the iron (III) chloride intramolecular alkyne …
dihydrobenzo [b] azepine derivatives involving the iron (III) chloride intramolecular alkyne …