Catalytic alkane C–H functionalization by carbene insertion of unactivated C (sp3)–H bonds
Y Pan, Y Wang, S Karmakar, P Sivaguru… - Organic Chemistry …, 2024 - pubs.rsc.org
The direct and selective C–H functionalization of unactivated alkanes has been an
outstanding yet challenging goal of modern synthetic chemistry. The metal-carbene-induced …
outstanding yet challenging goal of modern synthetic chemistry. The metal-carbene-induced …
A Comprehensive Review on Selective Catalytic Methods for Functionalization of Adamantane Scaffolds
MP Kumar, AS Annie, JN Solanke… - Asian Journal of …, 2024 - Wiley Online Library
Over the decades, conventional techniques have been reported for the direct conversion of
a substantial framework of adamantyl C (sp3)‐H/Br/COOH bonds to various C− C, C− N, and …
a substantial framework of adamantyl C (sp3)‐H/Br/COOH bonds to various C− C, C− N, and …
Regio-and stereoselective hydrosilylation of alkynes with alkoxysilanes for the synthesis of β-(Z) vinylsilanes catalyzed by a dirhodium (ii)/XantPhos complex
L Yang, W Lu, X Wu, Y Lu, X Xie… - Organic Chemistry …, 2024 - pubs.rsc.org
A Rh2 (OAc) 4/XantPhos ((9, 9-dimethyl-9H-xanthene-4, 5-diyl) bis (diphenylphosphane))
catalyzed regio-and stereoselective hydrosilylation of alkynes with various tertiary silanes in …
catalyzed regio-and stereoselective hydrosilylation of alkynes with various tertiary silanes in …
A Precise Route to Tetrasubstituted Allyl Amines via Regioselective Dicarbofunctionalization of Masked Propargyl Amines
Allyl amines are vital components in various biologically important molecules and play a
significant role in their function. Presently, most methods are geared toward the preparation …
significant role in their function. Presently, most methods are geared toward the preparation …
Oxidants Controlled C− H Bond Functionalization of N‐Aryltetrahydroisoquinolines: The Construction of the Quaternary Carbon Center and Cleavage of the C− N …
Y Chen, S Zhang, T Li, Q Ma, Y Yuan… - Chemistry–A European …, 2024 - Wiley Online Library
Initiated by triarylamine radical cation salt (TBPA), the direct C− H bond functionalization of α‐
N‐aryltetrahydroisoquinoline esters was smoothly realized, giving a series of α …
N‐aryltetrahydroisoquinoline esters was smoothly realized, giving a series of α …
Dirhodium (ii) complex catalyzed dehydrosilylation of styrenes: theoretical investigations on the mechanism, selectivity, and ligand effects
Z Zhong, Q Li, X Li - Physical Chemistry Chemical Physics, 2024 - pubs.rsc.org
The dirhodium (II) complexes with bridging phosphine and OAc ligands showed high
reactivity and selectivities in olefin dehydrosilylation. In order to determine the structure of …
reactivity and selectivities in olefin dehydrosilylation. In order to determine the structure of …
Modern Synthetic Strategy for Adamantyl Organometallic Reagents and Functionalization of Adamantyl Frameworks
V Dhayalan - ChemistrySelect, 2024 - Wiley Online Library
This short review article demonstrates recent techniques for the typical conversion of
adamantyl C (sp3)− Br bond to various C− C, C− N, and C− X bonds enabled by multiple …
adamantyl C (sp3)− Br bond to various C− C, C− N, and C− X bonds enabled by multiple …