Cross-Electrophile Coupling: Principles, Methods, and Applications in Synthesis

LE Ehehalt, OM Beleh, IC Priest, JM Mouat… - Chemical …, 2024 - ACS Publications
Cross-electrophile coupling (XEC), defined by us as the cross-coupling of two different σ-
electrophiles that is driven by catalyst reduction, has seen rapid progression in recent years …

Electrochemical methods for synthesis and in situ generation of organometallic compounds

ZN Gafurov, AO Kantyukov, AA Kagilev… - Coordination Chemistry …, 2021 - Elsevier
The electrochemical methods have a huge synthetic potential in both academia and
industry. However, the implementation of electrochemistry for the synthesis of …

Cross‐Electrophile C−PIII Coupling of Chlorophosphines with Organic Halides: Photoinduced PIII and Aminoalkyl Radical Generation Enabled by Pnictogen …

YL Tu, BB Zhang, BS Qiu, ZX Wang… - Angewandte Chemie …, 2023 - Wiley Online Library
Pnictogen bonding (PnB) has gained recognition as an appealing strategy for constructing
novel architectures and unlocking new properties. Within the synthetic community, the …

Photocatalytic C–P bond formation based on the reaction of carbon-centered radicals with phosphides

SY Zhao, YY Huang, SH Deng, ZP Guan… - Organic Chemistry …, 2024 - pubs.rsc.org
Organophosphorus compounds hold significant importance in the fields of materials
science, medicinal chemistry, pesticides and organic synthesis. In particular, phosphonate …

Copper-catalyzed synthesis of unsymmetrical triarylphosphines

DV Allen, D Venkataraman - The Journal of Organic Chemistry, 2003 - ACS Publications
Various triarylphosphines have been prepared by coupling diphenylphosphine with aryl
iodides with catalytic amounts of CuI in the presence of either K2CO3 or Cs2CO3, in good …

The role of organonickel reagents in organophosphorus chemistry

ZN Gafurov, AA Kagilev, AO Kantyukov… - Coordination Chemistry …, 2021 - Elsevier
Organonickel reagents are widely used for the obtaining of the organophosphorus
compounds from different phosphorus sources including elemental white phosphorus …

Electron transfer in organonickel complexes of α-diimines: Versatile redox catalysts for C–C or C–P coupling reactions–A review

A Klein, YH Budnikova, OG Sinyashin - Journal of organometallic chemistry, 2007 - Elsevier
Organonickel complexes with α-diimine ligands play an important role in electrocatalytic C–
C or C–P cross coupling reactions. The review summarises recent insights into the reaction …

Recent advances in electrochemical C—H phosphorylation

YH Budnikova, EL Dolengovsky, MV Tarasov… - Frontiers in …, 2022 - frontiersin.org
The activation of C–H bond, and its direct one-step functionalization, is one of the key
synthetic methodologies that provides direct access to a variety of practically significant …

Electrochemistry in organics: a powerful tool for “green” synthesis

YH Budnikova, EL Dolengovski, MV Tarasov… - Journal of Solid State …, 2024 - Springer
Advances in electro-organic synthesis are associated with searching for new innovative
synthetic approaches, especially those to synthesizing and functionalizing complex …

Electrochemical insight into mechanisms and metallocyclic intermediates of C− H functionalization

YH Budnikova - The Chemical Record, 2021 - Wiley Online Library
Transition metal‐catalyzed C− H activation has emerged as a powerful tool in organic
synthesis and electrosynthesis as well as in the development of new methodologies for …