Proton transport in metal–organic frameworks

DW Lim, H Kitagawa - Chemical reviews, 2020 - ACS Publications
Solid-state proton conductors (SSPCs), which are a key component for the safety and
efficiency of fuel cells, have received much attention due to their broad application in …

Water stability and adsorption in metal–organic frameworks

NC Burtch, H Jasuja, KS Walton - Chemical reviews, 2014 - ACS Publications
1. INTRODUCTION The ability to synthesize porous metal− organic frameworks (MOFs) with
prescribed structural features (Figure 1) has led to intense interest in the materials for …

Molecular sieving of ethylene from ethane using a rigid metal–organic framework

RB Lin, L Li, HL Zhou, H Wu, C He, S Li, R Krishna… - Nature materials, 2018 - nature.com
There are great challenges in developing efficient adsorbents to replace the currently used
and energy-intensive cryogenic distillation processes for olefin/paraffin separation, owing to …

Water adsorption in MOFs: fundamentals and applications

J Canivet, A Fateeva, Y Guo, B Coasne… - Chemical Society …, 2014 - pubs.rsc.org
This review article presents the fundamental and practical aspects of water adsorption in
Metal–Organic Frameworks (MOFs). The state of the art of MOF stability in water, a crucial …

Ion conductivity and transport by porous coordination polymers and metal–organic frameworks

S Horike, D Umeyama, S Kitagawa - Accounts of chemical …, 2013 - ACS Publications
Ion conduction and transport in solids are both interesting and useful and are found in
widely distinct materials, from those in battery-related technologies to those in biological …

A mechanochemically synthesized covalent organic framework as a proton-conducting solid electrolyte

DB Shinde, HB Aiyappa, M Bhadra… - Journal of Materials …, 2016 - pubs.rsc.org
Mechanochemistry has become an increasingly important synthetic tool for a waste-free
environment. However, the poor quality of the so-derived materials in terms of their …

Two‐in‐one: Inherent anhydrous and water‐assisted high proton conduction in a 3D metal–organic framework

SS Nagarkar, SM Unni, A Sharma… - Angewandte Chemie …, 2014 - Wiley Online Library
The development of solid‐state proton‐conducting materials with high conductivity that
operate under both anhydrous and humidified conditions is currently of great interest in fuel …

Ionic conductivity and potential application for fuel cell of a modified imine-based covalent organic framework

C Montoro, D Rodríguez-San-Miguel… - Journal of the …, 2017 - ACS Publications
We present the novel potential application of imine-based covalent organic frameworks
(COFs), formed by the direct Schiff reaction between 1, 3, 5-tris (4-aminophenyl) benzene …

Stable 2D heteroporous covalent organic frameworks for efficient ionic conduction

Z Xie, B Wang, Z Yang, X Yang, X Yu… - Angewandte Chemie …, 2019 - Wiley Online Library
Abstract Two‐dimensional (2D) covalent organic frameworks (COFs) feature open and
ordered one‐dimensional column nanochannels which offer immense possibilities for …

Highly Efficient Proton Conduction in the Metal–Organic Framework Material MFM-300(Cr)·SO4(H3O)2

J Chen, Q Mei, Y Chen, C Marsh, B An… - Journal of the …, 2022 - ACS Publications
The development of materials showing rapid proton conduction with a low activation energy
and stable performance over a wide temperature range is an important and challenging line …