Crystal engineering strategies towards halogen-bonded metal–organic multi-component solids: Salts, cocrystals and salt cocrystals

V Nemec, K Lisac, N Bedeković, L Fotović… - …, 2021 - pubs.rsc.org
Over the past several decades, halogen bonding has become a standard 'tool'in
supramolecular chemistry and particularly in crystal engineering. Traditionally, the study of …

Unravelling the potential of sigma hole-assisted co-crystallization: Highlighting recent developments

R Siddiqui, J Rani, HM Titi, R Patra - Coordination Chemistry Reviews, 2024 - Elsevier
In the past several decades, the field of cocrystal engineering has developed into a vital
research topic in supramolecular chemistry, holding the foremost scope in crystal …

Enhancing supramolecular assembly in bodipy derivatives: harnessing halogen bonding for cocrystal design

G Gümüşgöz Çelik, B Dedeoglu… - Crystal Growth & …, 2023 - ACS Publications
Supramolecular synthesis, a field of study in chemistry, offers a versatile approach to
construct complex structures using non-covalent interactions. In this study, we explore the …

[HTML][HTML] CF 3-substituted sulfonium cations as efficient chalcogen bond donors towards cyanometalates

TN Streit, RM Gomila, R Sievers, A Frontera… - …, 2024 - pubs.rsc.org
S–(CF3) Thianthrenium and S–(CF3) dibenzothiophenium cations form potent chalcogen
bonds (ChBs) with [Mo (CO) 5CN]−, yielding S2N2 supramolecular motifs. Crystal structures …

[HTML][HTML] Virtual issue on halogen bonding

M Hariharan - Crystal Growth & Design, 2022 - ACS Publications
Despite its identification in the early 19th century, the fundamental understanding of halogen
bonding continues to hold immense interest in crystal engineering and supramolecular …

Polymorphs and solid solutions: materials with new luminescent properties obtained through mechanochemical transformation of dicyanoaurate (i) salts

J Vainauskas, F Topić, M Arhangelskis, HM Titi… - Faraday …, 2023 - pubs.rsc.org
We report the use of mechano-and thermochemical methods to create new solid-state
luminescent materials from well-known inorganic salts, potassium dicyanoaurate (I) KAu …

[HTML][HTML] Structural diversity of supramolecular networks formed between polycyanometalates and sulfur-based chalcogen bond donors

TN Streit, J Langwald, RM Gomila, A Frontera… - …, 2024 - pubs.rsc.org
The co-crystallization of S-(CF3)-dibenzothiophenium (“Umemoto”–abbreviated Ume)
cations and polycyanometalates with different coordination geometries yields a large …

Two-dimensional Cd 3-based metal–organic frameworks with halogen bonding sites for the uptake of I 2

ZH Zhang, JL Ge, Y Li, Q Li, PP Ma, XY Tang… - …, 2023 - pubs.rsc.org
Developing porous materials for the efficient capture of I2 is relevant to the sequestration
and storage of radioactive iodine towards clean nuclear energy. In this work, three …

Cubic Three-Dimensional Networks of the Cyanometalate [Fe(CN)6]3 with the Ditopic Halogen Bond Donor Diiodoacetylene C2I2

M Sellin, SM Rupf, M Malischewski - Crystal Growth & Design, 2021 - ACS Publications
Halogen-bonded networks have been prepared by cocrystallization of the linear ditopic
halogen bond donor diiodoacetylene C2I2 and lipophilic phosphonium salts of the …

Carbon-atom hybridization tunes the halogen-bond strength in the series of DABCO· C2H2nI2 (n= 0–2) cocrystals

Y Torubaev, I Skabitskiy - Acta Crystallographica Section C …, 2022 - journals.iucr.org
Two new cocrystals of 1, 4-diazabicyclo [2.2. 2] octane (DABCO, C6H12N2) with 1, 2-
diiodoethene (1, 2-C2H2I2) and 1, 2-diiodoethane (1, 2-C2H4I2) complete a series of …