Sulfur-bridged chromophores for photofunctional materials: using sulfur oxidation state to tune electronic and structural properties

J Yuan, Z Xu, MO Wolf - Chemical Science, 2022 - pubs.rsc.org
The use of a heteroatom, such as sulfur, as a linker or bridge, in π-conjugated materials has
advantages over purely carbon-based ones due to the accessibility of higher oxidation …

Synthesis of thiiranes by direct sulfur transfer: The challenge of developing effective sulfur donors and metal catalysts

W Adam, RM Bargon - Chemical reviews, 2004 - ACS Publications
The first thiirane, a saturated three-memberedring heterocycle with one sulfur atom, also
named episulfide or thioepoxide, was synthesized by Staudinger and Pfenninger in 1916, 1 …

Frustrated Lewis Pair Activation of an N‐Sulfinylamine: A Source of Sulfur Monoxide

LE Longobardi, V Wolter… - Angewandte Chemie …, 2015 - Wiley Online Library
Inter‐and intramolecular P/B frustrated Lewis pairs are shown to react with an N‐
sulfinylamine to form PNSOB linakages. These species can be regarded as phosphinimine …

Identification of carbonyl sulfide and sulfur dioxide in porcine coronary artery by gas chromatography/mass spectrometry, possible relevance to EDHF

M Balazy, IA Abu-Yousef, DN Harpp, J Park - Biochemical and Biophysical …, 2003 - Elsevier
Incubation of porcine coronary artery rings and cardiac muscle tissue in Krebs buffer
followed by GC/MS analysis of the headspace gas revealed two gases, carbonyl sulfide …

Sulfur Monoxide Transfer from peri-Substituted Trisulfide-2-oxides to Dienes: Substituent Effects, Mechanistic Studies and Application in Thiophene Synthesis

RS Grainger, B Patel, BM Kariuki, L Male… - Journal of the …, 2011 - ACS Publications
Three peri-substituted trisulfide-2-oxides are prepared by treatment of 1, 8-naphthalene
dithiols with thionyl chloride and pyridine. The 1, 2, 3-trithiane-2-oxide ring adopts a sofa …

Crystalline, room-temperature stable phosphine–SO 2 adducts: generation of sulfur monoxide from sulfur dioxide

F Buß, P Rotering, C Mück-Lichtenfeld… - Dalton Transactions, 2018 - pubs.rsc.org
The particularly basic phosphines 1a–c readily form isolable, zwitterionic Lewis base
adducts with SO2 that were fully characterized including by X-ray diffraction studies …

Sulfur monoxide thermal release from an anthracene-based precursor, spectroscopic identification, and transfer reactivity

M Joost, M Nava, WJ Transue… - Proceedings of the …, 2018 - National Acad Sciences
Sulfur monoxide (SO) is a highly reactive molecule and thus, eludes bulk isolation. We
report here on synthesis and reactivity of a molecular precursor for SO generation, namely 7 …

A Sulfur Monoxide Surrogate Designed for the Synthesis of Sulfoxides and Sulfinamides

D Austrup, F Saito - Angewandte Chemie, 2023 - Wiley Online Library
Sulfur monoxide (SO) is a highly reactive species that cannot be isolated in bulk. However,
SO can play a pivotal role as a fundamental building block in organic synthesis. Reported …

Reactivity of small oxoacids of sulfur

SV Makarov, AK Horváth, AS Makarova - Molecules, 2019 - mdpi.com
Oxidation of sulfide to sulfate is known to consist of several steps. Key intermediates in this
process are the so-called small oxoacids of sulfur (SOS)—sulfenic HSOH (hydrogen …

A novel recyclable sulfur monoxide transfer reagent

RS Grainger, A Procopio, JW Steed - Organic Letters, 2001 - ACS Publications
Trisulfide 2-oxide 11 has been prepared from disulfide 9 via reduction to the corresponding
dithiol and subsequent trapping with thionyl chloride. Heating trisulfide oxide 11 in the …