Sulfur-bridged chromophores for photofunctional materials: using sulfur oxidation state to tune electronic and structural properties
The use of a heteroatom, such as sulfur, as a linker or bridge, in π-conjugated materials has
advantages over purely carbon-based ones due to the accessibility of higher oxidation …
advantages over purely carbon-based ones due to the accessibility of higher oxidation …
Synthesis of thiiranes by direct sulfur transfer: The challenge of developing effective sulfur donors and metal catalysts
W Adam, RM Bargon - Chemical reviews, 2004 - ACS Publications
The first thiirane, a saturated three-memberedring heterocycle with one sulfur atom, also
named episulfide or thioepoxide, was synthesized by Staudinger and Pfenninger in 1916, 1 …
named episulfide or thioepoxide, was synthesized by Staudinger and Pfenninger in 1916, 1 …
Frustrated Lewis Pair Activation of an N‐Sulfinylamine: A Source of Sulfur Monoxide
LE Longobardi, V Wolter… - Angewandte Chemie …, 2015 - Wiley Online Library
Inter‐and intramolecular P/B frustrated Lewis pairs are shown to react with an N‐
sulfinylamine to form PNSOB linakages. These species can be regarded as phosphinimine …
sulfinylamine to form PNSOB linakages. These species can be regarded as phosphinimine …
Identification of carbonyl sulfide and sulfur dioxide in porcine coronary artery by gas chromatography/mass spectrometry, possible relevance to EDHF
M Balazy, IA Abu-Yousef, DN Harpp, J Park - Biochemical and Biophysical …, 2003 - Elsevier
Incubation of porcine coronary artery rings and cardiac muscle tissue in Krebs buffer
followed by GC/MS analysis of the headspace gas revealed two gases, carbonyl sulfide …
followed by GC/MS analysis of the headspace gas revealed two gases, carbonyl sulfide …
Sulfur Monoxide Transfer from peri-Substituted Trisulfide-2-oxides to Dienes: Substituent Effects, Mechanistic Studies and Application in Thiophene Synthesis
Three peri-substituted trisulfide-2-oxides are prepared by treatment of 1, 8-naphthalene
dithiols with thionyl chloride and pyridine. The 1, 2, 3-trithiane-2-oxide ring adopts a sofa …
dithiols with thionyl chloride and pyridine. The 1, 2, 3-trithiane-2-oxide ring adopts a sofa …
Crystalline, room-temperature stable phosphine–SO 2 adducts: generation of sulfur monoxide from sulfur dioxide
F Buß, P Rotering, C Mück-Lichtenfeld… - Dalton Transactions, 2018 - pubs.rsc.org
The particularly basic phosphines 1a–c readily form isolable, zwitterionic Lewis base
adducts with SO2 that were fully characterized including by X-ray diffraction studies …
adducts with SO2 that were fully characterized including by X-ray diffraction studies …
Sulfur monoxide thermal release from an anthracene-based precursor, spectroscopic identification, and transfer reactivity
M Joost, M Nava, WJ Transue… - Proceedings of the …, 2018 - National Acad Sciences
Sulfur monoxide (SO) is a highly reactive molecule and thus, eludes bulk isolation. We
report here on synthesis and reactivity of a molecular precursor for SO generation, namely 7 …
report here on synthesis and reactivity of a molecular precursor for SO generation, namely 7 …
A Sulfur Monoxide Surrogate Designed for the Synthesis of Sulfoxides and Sulfinamides
D Austrup, F Saito - Angewandte Chemie, 2023 - Wiley Online Library
Sulfur monoxide (SO) is a highly reactive species that cannot be isolated in bulk. However,
SO can play a pivotal role as a fundamental building block in organic synthesis. Reported …
SO can play a pivotal role as a fundamental building block in organic synthesis. Reported …
Reactivity of small oxoacids of sulfur
SV Makarov, AK Horváth, AS Makarova - Molecules, 2019 - mdpi.com
Oxidation of sulfide to sulfate is known to consist of several steps. Key intermediates in this
process are the so-called small oxoacids of sulfur (SOS)—sulfenic HSOH (hydrogen …
process are the so-called small oxoacids of sulfur (SOS)—sulfenic HSOH (hydrogen …
A novel recyclable sulfur monoxide transfer reagent
RS Grainger, A Procopio, JW Steed - Organic Letters, 2001 - ACS Publications
Trisulfide 2-oxide 11 has been prepared from disulfide 9 via reduction to the corresponding
dithiol and subsequent trapping with thionyl chloride. Heating trisulfide oxide 11 in the …
dithiol and subsequent trapping with thionyl chloride. Heating trisulfide oxide 11 in the …