Effective PFAS degradation by electrochemical oxidation methods-recent progress and requirement

M Mirabediny, J Sun, TT Yu, B Åkermark, B Das… - Chemosphere, 2023 - Elsevier
The presence of per-and poly-fluoroalkyl substances (PFASs) in water is of global concern
due to their high stability and toxicity even at very low concentrations. There are several …

Tropospheric aqueous‐phase free‐radical chemistry: Radical sources, spectra, reaction kinetics and prediction tools

H Herrmann, D Hoffmann, T Schaefer… - …, 2010 - Wiley Online Library
The most important radicals which need to be considered for the description of chemical
conversion processes in tropospheric aqueous systems are the hydroxyl radical (OH), the …

Density functional theory calculations for insight into the heterocatalyst reactivity and mechanism in persulfate-based advanced oxidation reactions

P Zhang, Y Yang, X Duan, Y Liu, S Wang - ACS catalysis, 2021 - ACS Publications
Advanced oxidation processes (AOPs) based on persulfates such as peroxymonosulfate
and peroxydisulfate via heterogeneous catalysts have been a research hotspot due to their …

Reducing the discharge of micropollutants in the aquatic environment: the benefits of upgrading wastewater treatment plants

RIL Eggen, J Hollender, A Joss, M Schärer, C Stamm - 2014 - ACS Publications
Micropollutants (MPs) as individual compounds or in complex mixtures are relevant for water
quality and may trigger unwanted ecological effects. MPs originate from different point and …

Quantitative structure–activity relationship (QSAR) for the oxidation of trace organic contaminants by sulfate radical

R Xiao, T Ye, Z Wei, S Luo, Z Yang… - … science & technology, 2015 - ACS Publications
The sulfate radical anion (SO4•–) based oxidation of trace organic contaminants (TrOCs)
has recently received great attention due to its high reactivity and low selectivity. In this …

pySiRC”: Machine Learning Combined with Molecular Fingerprints to Predict the Reaction Rate Constant of the Radical-Based Oxidation Processes of Aqueous …

FO Sanches-Neto, JR Dias-Silva… - Environmental …, 2021 - ACS Publications
We developed a web application structured in a machine learning and molecular fingerprint
algorithm for the automatic calculation of the reaction rate constant of the oxidative …

Magnetic visible-light activated photocatalyst CuFe2O4/Bi2WO6/mpg-C3N4 for the treatment of natural organic matter

HB Truong, BT Huy, YI Lee, HT Nguyen, J Cho… - Chemical Engineering …, 2023 - Elsevier
Despite growing interest in research on visible-light-driven photocatalysts, reusable
photocatalysts have not been extensively developed for the treatment of natural organic …

Shedding light on “Black Box” machine learning models for predicting the reactivity of HO radicals toward organic compounds

S Zhong, K Zhang, D Wang, H Zhang - Chemical Engineering Journal, 2021 - Elsevier
Developing quantitative structure-activity relationships (QSARs) is an important approach to
predicting the reactivity of HO radicals toward newly emerged organic compounds. As …

A deep neural network combined with molecular fingerprints (DNN-MF) to develop predictive models for hydroxyl radical rate constants of water contaminants

S Zhong, J Hu, X Fan, X Yu, H Zhang - Journal of hazardous materials, 2020 - Elsevier
This work combined a Deep Neural Network (DNN) with molecular fingerprints (MF) to
develop models to predict the OH radical dot radical rate constants of 593 organic …

Using floating photocatalyst mpg-C3N4/expanded perlite to treat natural organic matter under visible light

HB Truong, I Rabani, BT Huy, NHT Tran… - Chemical Engineering …, 2023 - Elsevier
In-situ application of powdered photocatalysts in water systems is particularly challenging
owing to intrinsic hurdles, such as submersion in water without stirring, limited light …