Carbonylation of ethene catalysed by Pd (II)-phosphine complexes

G Cavinato, L Toniolo - Molecules, 2014 - mdpi.com
This review deals with olefin carbonylation catalysed by Pd (II)-phosphine complexes in
protic solvents. In particular, the results obtained in the carbonylation with ethene are …

Kinetics and mechanisms of homogeneous catalytic reactions. Part 12. Hydroalcoxycarbonylation of 1-hexene using palladium/triphenylphosphine systems as catalyst …

M Rosales, I Pacheco, J Medina, J Fernández… - Catalysis Letters, 2014 - Springer
Abstract Systems prepared in situ by addition of n equivalents of triphenylphosphine to
palladium dichloride in the presence of m equivalents of para-toluenesulfonic acid (TSA) …

Application of transition metals in hydroformylation annual survey covering the year 2001

F Ungváry - Coordination chemistry reviews, 2002 - Elsevier
Application of transition metals in hydroformylation annual survey covering the year 2001 -
ScienceDirect Skip to main contentSkip to article Elsevier logo Journals & Books Search …

Intramolecularly Stabilised Group 10 Metal Stannyl and Stannylene Complexes: Multi‐pathway Synthesis and Observation of Platinum‐to‐Tin Alkyl Transfer

S Warsink, EJ Derrah, CA Boon… - … A European Journal, 2015 - Wiley Online Library
Abstract Reaction of [PdClMe (P^ N) 2] with SnCl2 followed by Cl‐abstraction leads to
apparent Pd C bond activation, resulting in methylstannylene species trans‐[PdCl {(P^ N) …

Rhodium-catalyzed hydroformylation of 4-vinylpyridine: 4-ethylpyridine formation via an unusual cleavage of the Rh− C bond by the enolic form of the oxo product

R Lazzaroni, R Settambolo, A Caiazzo… - …, 2002 - ACS Publications
The hydroformylation of 4-vinylpyridine (4VP) with rhodium catalyst Rh4 (CO) 12 modified
with phosphine ligands (PMe2Ph) is not completely chemoselective to the branched …

Acenaphtene-1-carboxylic acid methyl ester by palladium-catalyzed chemoselective hydroesterification of acenaphthylene

J Gironès, J Duran, A Polo, J Real - Journal of Molecular Catalysis A …, 2003 - Elsevier
The hydroesterification of acenaphthylene with carbon monoxide and methanol, catalyzed
by PdII/PR3 systems (PR3= PPh3, P (o-MeC6H4) 3, P (p-MeC6H4) 3, P (p-FC6H4) 3, P (iBu) …

Enantioselectivity in the catalytic hydroesterification of acenaphthylene: direct evidence of the racemization of Pd II-alkyl species by a degenerate substitution …

J Gironès, J Duran, A Polo, J Real - Chemical communications, 2003 - pubs.rsc.org
The palladium catalyzed hydroesterification of acenaphthylene takes place through a
“hydride” mechanism, that is, through the selective cis insertion of the olefin into the …

Selective Catalytic Hydrocarboxylation and Deuterocarboxylation of Allyl Cyanide to Cyanobutanoic Acids with Monodentate and Bidentate Phosphines

O Vallcorba, A Polo, J Real - ChemCatChem, 2017 - Wiley Online Library
The hydrocarboxylation of allyl cyanide with monodentate phosphine systems (Pd/
triphenylphosphine and protic acid cocatalyst) gave branched 3‐cyano‐2‐methylpropanoic …

[PDF][PDF] Merlín Rosales, Inés Pacheco, Jairo Medina, Juan Fernández, Ángel González, Rodolfo Izquierdo, Luis G. Melean & Pablo J. Baricelli

CR Part - Catal Lett, 2014 - researchgate.net
Abstract Systems prepared in situ by addition of n equivalents of triphenylphosphine to
palladium dichloride in the presence of m equivalents ofpara-toluenesulfonic acid (TSA) …