This review covers the use of 2-azaallyl anions, 2-azaallyl cations, and 2-azaallyl radicals in
organic synthesis up through June 2018. Particular attention is paid to both foundational …

Reactions that utilize addition of active C− H nucleophiles to C X bonds represent some of
the most fundamental carbon− carbon bond-forming processes in organic chemistry. Of …

Direct and rapid heating by microwave irradiation in combination with sealed vessel
processing in many cases enables reactions to be carried out in a fraction of the time …

Evaluating the aromaticity of a molecular system and the influence of this concept on its
properties is a crucial step in the development of novel aromatic systems. Modern …

Under control: A chiral imidazoline–aminophenol/Ni (OAc) 2 complex promotes the first
catalytic asymmetric exo′‐selective [3+ 2] cycloaddition of iminoesters and nitroalkenes …

The (3+ 2) cycloaddition between azomethine ylides and alkenes is an efficient, convergent
and stereocontrolled method for the synthesis of unnatural pyrrolidine and proline scaffolds …

In the oriented external electric-field-driven catalysis, the reaction rates and the selectivity of
chemical reactions can be tuned at will. The activation barriers of chemical reactions within …

The aim of this work was to determine the parameters that have decisive roles in microwave‐
assisted reactions and to develop a model, using computational chemistry, to predict a priori …

Abstract The 1, 3‐dipolar cycloaddition reactions (DCs) of nitrile oxides (NOs) to alkenes
and alkynes are useful methods for the synthesis of 2‐isoxazolines and isoxazoles …

A Lewis base-catalyzed three-component cascade reaction was developed for the synthesis
of 4, 5-disubstituted-1, 2, 3-(NH)-triazoles. More than 25 new (NH)-triazoles were prepared …