The Current Understanding of Mechanistic Pathways in Zeolite Crystallization

AJ Mallette, K Shilpa, JD Rimer - Chemical Reviews, 2024 - ACS Publications
Zeolite catalysts and adsorbents have been an integral part of many commercial processes
and are projected to play a significant role in emerging technologies to address the …

Crystal growth with macromolecular additives

AG Shtukenberg, MD Ward, B Kahr - Chemical reviews, 2017 - ACS Publications
Interactions of macromolecules with growing crystalline surfaces play an important role in
biomineralization, determine survival of some organisms at low temperatures, and offer a …

[HTML][HTML] Tautomerism unveils a self-inhibition mechanism of crystallization

W Tang, T Yang, CA Morales-Rivera, X Geng… - Nature …, 2023 - nature.com
Modifiers are commonly used in natural, biological, and synthetic crystallization to tailor the
growth of diverse materials. Here, we identify tautomers as a new class of modifiers where …

Silanol-engineered nonclassical growth of zeolite nanosheets from oriented attachment of amorphous protozeolite nanoparticles

Q Zhang, J Li, X Wang, G He, L Li, J Xu… - Journal of the …, 2023 - ACS Publications
Zeolite nonclassical growth via particle attachment has been proposed for two decades, yet
the attachment mechanism and kinetic regulation remain elusive. Here, nonclassical growth …

[HTML][HTML] Preparation of ZnO nanoparticles with high dispersibility based on oriented attachment (OA) process

D Cao, S Gong, X Shu, D Zhu, S Liang - Nanoscale research letters, 2019 - Springer
Understanding nanoparticle growth mechanisms is crucial for the synthesis of nanocrystals
with desired biological and chemical properties. Growth of nanocrystals by oriented …

Perspectives on the current state, challenges, and opportunities in pharmaceutical crystallization process development

A Cote, D Erdemir, KP Girard, DA Green… - Crystal Growth & …, 2020 - ACS Publications
Crystallization is the primary process used to purify synthetic drug substances and
intermediates as well as to control bulk properties, including particle size, surface area, and …

[HTML][HTML] Lipid-coated ZnO nanoparticles synthesis, characterization and cytotoxicity studies in cancer cell

D Cao, X Shu, D Zhu, S Liang, M Hasan, S Gong - Nano Convergence, 2020 - Springer
ZnO nanoparticles are widely used in biological, chemical, and medical fields, but their
toxicity impedes their wide application. In this study, pristine ZnO NPs (~ 7 nm;~ 18 nm;~ 49 …

Molecular imposters functioning as versatile growth modifiers of urate crystallization

W Tang, C Smith, CB Parry, J Meegan… - Crystal Growth & …, 2023 - ACS Publications
Interactions between molecular modifiers and crystal surfaces govern numerous processes
and structural outcomes of natural, biological, and synthetic crystallization. An efficient …

Ultrafast synthesis of zeolites: breakthrough, progress and perspective

Z Liu, J Zhu, T Wakihara, T Okubo - Inorganic Chemistry Frontiers, 2019 - pubs.rsc.org
Zeolites maintain the momentum of their existing applications and continue to find new
applications in the fields of catalysis and separation. Such application prospects call for an …

[HTML][HTML] Switching between classical/nonclassical crystallization pathways of TS-1 zeolite: implication on titanium distribution and catalysis

R Bai, Y Song, L Lätsch, Y Zou, Z Feng, C Copéret… - Chemical …, 2022 - pubs.rsc.org
In the MFI zeolite crystallization process, the classical crystallization mechanism based upon
the addition of silica species is often concomitant with the nonclassical route that is …