Nitrogen fixation via splitting into nitrido complexes
SJK Forrest, B Schluschaß, EY Yuzik-Klimova… - Chemical …, 2021 - ACS Publications
The large carbon footprint of the Haber–Bosch process, which provides ammonia for
fertilizers but also the feedstock for all nitrogenous commercial products, has fueled the …
fertilizers but also the feedstock for all nitrogenous commercial products, has fueled the …
Catalytic N2-to-NH3 (or -N2H4) Conversion by Well-Defined Molecular Coordination Complexes
Nitrogen fixation, the six-electron/six-proton reduction of N2, to give NH3, is one of the most
challenging and important chemical transformations. Notwithstanding the barriers …
challenging and important chemical transformations. Notwithstanding the barriers …
Beyond ammonia: nitrogen–element bond forming reactions with coordinated dinitrogen
The functionalization of coordinated dinitrogen to form nitrogen–element bonds en route to
nitrogen-containing molecules is a long-standing challenge in chemical synthesis. The …
nitrogen-containing molecules is a long-standing challenge in chemical synthesis. The …
Activation of dinitrogen by polynuclear metal complexes
Activation of dinitrogen plays an important role in daily anthropogenic life, and the processes
by which this fixation occurs have been a longstanding and significant research focus within …
by which this fixation occurs have been a longstanding and significant research focus within …
Examining the relationship between coordination mode and reactivity of dinitrogen
RJ Burford, MD Fryzuk - Nature Reviews Chemistry, 2017 - nature.com
Molecular nitrogen (N2) is the most abundant gas in Earth's atmosphere, but its low reactivity
has hampered its use as a precursor to higher value nitrogen-containing compounds …
has hampered its use as a precursor to higher value nitrogen-containing compounds …
Kinetic isotope effects in the study of organometallic reaction mechanisms
M Gomez-Gallego, MA Sierra - Chemical reviews, 2011 - ACS Publications
Kinetic Isotope Effects in the Study of Organometallic Reaction Mechanisms | Chemical
Reviews ACS ACS Publications C&EN CAS Find my institution Log In Chemical Reviews ACS …
Reviews ACS ACS Publications C&EN CAS Find my institution Log In Chemical Reviews ACS …
Design and optimization of catalysts based on mechanistic insights derived from quantum chemical reaction modeling
Until recently, computational tools were mainly used to explain chemical reactions after
experimental results were obtained. With the rapid development of software and hardware …
experimental results were obtained. With the rapid development of software and hardware …
Developing more sustainable processes for ammonia synthesis
Y Tanabe, Y Nishibayashi - Coordination Chemistry Reviews, 2013 - Elsevier
This paper describes a recent advance on the conversion of molecular dinitrogen into
ammonia or ammonia equivalent, silylamine, by using transition metal–dinitrogen …
ammonia or ammonia equivalent, silylamine, by using transition metal–dinitrogen …
Dinitrogen coordination chemistry: on the biomimetic borderlands
BA MacKay, MD Fryzuk - Chemical reviews, 2004 - ACS Publications
Biological nitrogen fixation by the nitrogenase enzymes has long been a touchstone for
dinitrogen chemists. 1, 2 Both the enzymatic reduction and protonation of N2 mediated by …
dinitrogen chemists. 1, 2 Both the enzymatic reduction and protonation of N2 mediated by …
Catalytic reduction of dinitrogen to ammonia at a single molybdenum center
RR Schrock - Accounts of chemical research, 2005 - ACS Publications
This Account explores the catalytic reduction of dinitrogen by molybdenum complexes that
contain the [HIPTN3N] 3-ligand ([HIPTN3N] 3-=[(HIPTNCH2CH2) 3N] 3-, where HIPT= 3, 5 …
contain the [HIPTN3N] 3-ligand ([HIPTN3N] 3-=[(HIPTNCH2CH2) 3N] 3-, where HIPT= 3, 5 …