Transition metal-catalysed direct borylation of hydrocarbons via C–H bond activation has
received a remarkable level of attention as a popular reaction in the synthesis of …

Organoboron reagents represent a unique class of compounds because of their utility in
modern synthetic organic chemistry, often affording unprecedented reactivity. The …

Transition metal-catalysed functionalizations of inert C–H bonds to construct C–C bonds
represent an ideal route in the synthesis of valuable organic molecules. Fine tuning of …

Conspectus Aromatic structures are widespread motifs throughout organic chemistry, and C–
H activation has been recognized as a major tool for enabling their sustainable and efficient …

Electrooxidation has emerged as an increasingly viable platform in molecular syntheses that
can avoid stoichiometric chemical redox agents. Despite major progress in electrochemical …

Regioselective functionalization of arenes remains a challenging problem in organic
synthesis. Steric interactions are often used to block sites adjacent to a given substituent, but …

Chalcogenide motifs are present as principal moieties in a vast array of natural products and
complex molecules. Till date, the construction of these chalcogen motifs has been restricted …

Catalytic C–H oxyfunctionalization reactions have garnered significant attention in recent
years with their ability to streamline synthetic routes toward complex molecules …

Electrophotochemistry has enabled arene C− H trifluoromethylation with the Langlois
reagent CF3SO2Na under mild reaction conditions. The merger of electrosynthesis and …

Pd (II)-catalyzed nondirected C–H functionalization of heteroarenes is a significant
challenge for the following reasons: poor reactivity of electron-deficient heterocycles and the …