The golden age of transfer hydrogenation
D Wang, D Astruc - Chemical reviews, 2015 - ACS Publications
Hydrogenation is one of the most fundamental transformations in organic synthesis, and its
industrial applications span from fine chemicals to pharmaceuticals synthesis. 1− 3 Direct …
industrial applications span from fine chemicals to pharmaceuticals synthesis. 1− 3 Direct …
The chiral boronate-catalyzed asymmetric transfer hydrogenation of various aromatic ketones to high-value alcohols: Preparation and spectroscopic studies
This work deals with the synthesis, spectroscopic studies and catalytic evaluation of the
novel chiral salen (L 1 H 2) and (L 2 H 2) ligands and their chiral boronate [L 1 (B 1-4)] and …
novel chiral salen (L 1 H 2) and (L 2 H 2) ligands and their chiral boronate [L 1 (B 1-4)] and …
Imidazolium ion tethered TsDPENs as efficient water-soluble ligands for rhodium catalyzed asymmetric transfer hydrogenation of aromatic ketones
An imidazolium ion tethered TsDPEN has been synthesized readily and used as a water-
soluble ligand for [Cp* RhCl 2] 2 catalyzed asymmetric transfer hydrogenation (ATH) of …
soluble ligand for [Cp* RhCl 2] 2 catalyzed asymmetric transfer hydrogenation (ATH) of …
The first application of C2-symmetric ferrocenyl phosphinite ligands for rhodium-catalyzed asymmetric transfer hydrogenation of various ketones
Homogeneous catalysis has been responsible for many major recent developments in
synthetic organic chemistry. The combined use of organometallic and coordination …
synthetic organic chemistry. The combined use of organometallic and coordination …
Well designed iridium-phosphinite complexes: Biological assays, electrochemical behavior and density functional theory calculations
Mononuclear phosphinite Iridium complexes based on ferrocene group have been prepared
and characterized by various spectroscopic techniques. The complexes were subjected to …
and characterized by various spectroscopic techniques. The complexes were subjected to …
Novel Mononuclear Metal-Phosphinite Compounds And Catalytic Performance In Transfer Hydrogenation Of Ketones
Since the obtained chiral alcohols are rather useful as well as biologically active
compounds, reduction of ketones to their respective alcohols is a crucial topic in synthetic …
compounds, reduction of ketones to their respective alcohols is a crucial topic in synthetic …
Enantioselective transfer hydrogenation of various ketones with novel efficient iridium (III) ferrocenyl-phosphinite catalysts
N Meric, M Aydemir - Journal of Organometallic Chemistry, 2016 - Elsevier
The asymmetric reduction of prochiral ketones is a pivotal reaction for the preparation of
chiral alcohols which form an extremely important class of intermediates for fine chemicals …
chiral alcohols which form an extremely important class of intermediates for fine chemicals …
Novel pyrazolylphosphite–and pyrazolylphosphinite–ruthenium (ii) complexes as catalysts for hydrogenation of acetophenone
The new compounds and potential ligands 2-(3, 5-di-tert-butyl-1H-pyrazol-1-yl)
ethyldiphenlyphosphinite (L1), 2-(3, 5-di-tert-butyl-1H-pyrazol-1-yl) ethyldiethylphosphite …
ethyldiphenlyphosphinite (L1), 2-(3, 5-di-tert-butyl-1H-pyrazol-1-yl) ethyldiethylphosphite …
Catalysts for the asymmetric transfer hydrogenation of various ketones from [3-[(2S)-2-[(diphenylphosphanyl) oxy]-3-phenoxypropyl]-1-methyl-1H-imidazol-3-ium …
Abstract The combination of [3-[(2S)-2-[(diphenylphosphanyl) oxy]-3-phenoxypropyl]-1-
methyl-1H-imidazol-3-ium chloride] with [Ru (η 6-arene)(μ-Cl) Cl] 2, Ir (η 5-C 5 Me 5)(μ-Cl) …
methyl-1H-imidazol-3-ium chloride] with [Ru (η 6-arene)(μ-Cl) Cl] 2, Ir (η 5-C 5 Me 5)(μ-Cl) …
Highly efficient iridium catalysts based on C2-symmetric ferrocenyl phosphinite ligands for asymmetric transfer hydrogenations of aromatic ketones
A series of chiral modular C 2-symmetric ferrocenyl phosphinite ligands have been
synthesized in good yields by using 1, 1′-ferrocenedicarboxyaldehyde and various amino …
synthesized in good yields by using 1, 1′-ferrocenedicarboxyaldehyde and various amino …