Intramolecular (directed) electrophilic C–H borylation
SA Iqbal, J Pahl, K Yuan, MJ Ingleson - Chemical Society Reviews, 2020 - pubs.rsc.org
The intramolecular C–H borylation of (hetero) arenes and alkenes using electrophilic
boranes is a powerful transition metal free methodology for forming C–B bonds. These C–H …
boranes is a powerful transition metal free methodology for forming C–B bonds. These C–H …
Recent advances in the synthesis of luminescent tetra-coordinated boron compounds
Tetra-coordinated boron compounds offer a plethora of luminescent materials. Different
chelation around the boron center (O, O-, N, C-, N, O-, and N, N-) has been explored to tune …
chelation around the boron center (O, O-, N, C-, N, O-, and N, N-) has been explored to tune …
Boron‐Thioketonates: A New Class of S, O‐Chelated Boranes as Acceptors in Optoelectronic Devices
Abstract Development of new n‐type semiconductors with tunable band gap and dielectric
constant has significant implication in dissociating bound charge carrier relevant for …
constant has significant implication in dissociating bound charge carrier relevant for …
Going beyond the borders: pyrrolo [3, 2-b] pyrroles with deep red emission
M Tasior, P Kowalczyk, M Przybył, M Czichy… - Chemical …, 2021 - pubs.rsc.org
A two-step route to strongly absorbing and efficiently orange to deep red fluorescent, doubly
B/N-doped, ladder-type pyrrolo [3, 2-b] pyrroles has been developed. We synthesize and …
B/N-doped, ladder-type pyrrolo [3, 2-b] pyrroles has been developed. We synthesize and …
Metal-Free Boron-Mediated ortho-C–H Hydroxylation of N-Benzyl-3,4,5-tribromopyrazoles
G Wu, Z Yang, X Xu, L Hao, L Chen, Y Wang… - Organic Letters, 2022 - ACS Publications
A novel route has been reported for C–H hydroxylation of benzyl compounds directed by a
3, 4, 5-tribromopyrazole auxiliary via boronation/oxidation using BBr3 and NaBO3· 4H2O …
3, 4, 5-tribromopyrazole auxiliary via boronation/oxidation using BBr3 and NaBO3· 4H2O …
B− N Coordinated Phenanthroimidazole‐Based Zinc‐Salen as a Photocatalyst for the Synthesis of Oxazolidinones using Carbon Dioxide as a C1 Source under Mild …
P Nayak, A Chandrasekar Murali… - Advanced Synthesis …, 2023 - Wiley Online Library
Cycloaddition of carbon dioxide (CO2) with aziridine catalyzed by a zinc‐salen having B− N
coordinated phenanthroimidazole motif as a photocatalyst (1), at 1 bar CO2 pressure and …
coordinated phenanthroimidazole motif as a photocatalyst (1), at 1 bar CO2 pressure and …
Tetra-Coordinated Boron-Functionalized Phenanthroimidazole-Based Zinc Salen as a Photocatalyst for the Cycloaddition of CO2 and Epoxides
A unique B–N coordinated phenanthroimidazole-based zinc salen was synthesized. The
zinc salen thus synthesized acts as a photocatalyst for the cycloaddition of carbon dioxide …
zinc salen thus synthesized acts as a photocatalyst for the cycloaddition of carbon dioxide …
Blue emissive amidinate-based tetra-coordinated boron compounds
A series of novel amidinate ligated four-coordinated boron compounds,[(Ar)-C (tBuN)
2BF2](1BF2–6BF2), were synthesised and structurally characterised (Ar= 1-phenyl, 2 …
2BF2](1BF2–6BF2), were synthesised and structurally characterised (Ar= 1-phenyl, 2 …
Pyrrolic type N directed borylation route to BN-PAHs: tuning the photophysical properties by varying the conjugation shape and size
Y Zhang, C Zhang, Y Guo, J Ye, B Zhen… - The Journal of …, 2021 - ACS Publications
Two series of BN-cyclopenta [a] phenalenes have been synthesized through an
indole/pyrrole oriented borylation reaction. A total of five compounds are obtained and fully …
indole/pyrrole oriented borylation reaction. A total of five compounds are obtained and fully …
Triarylborane‐appended anils and boranils: solid‐state emission, mechanofluorochromism, and phosphorescence
RP Nandi, P Sudhakar… - … A European Journal, 2020 - Wiley Online Library
Herein, the design, synthesis, optical properties, and mechanofluorochromism
characteristics of a series of conjugates having covalently linked triarylborane (TAB) and …
characteristics of a series of conjugates having covalently linked triarylborane (TAB) and …