Exploration of earth-abundant transition metals (Fe, Co, and Ni) as catalysts in unreactive chemical bond activations
Conspectus Activation of inert chemical bonds, such as C–H, C–O, C–C, and so on, is a very
important area, to which has been drawn much attention by chemists for a long time and …
important area, to which has been drawn much attention by chemists for a long time and …
From models to lignin: Transition metal catalysis for selective bond cleavage reactions
PJ Deuss, K Barta - Coordination Chemistry Reviews, 2016 - Elsevier
In the coming decades major changes are expected in the chemical industry regarding the
utilized raw material inputs. Depleting fossil resources will gradually be replaced by …
utilized raw material inputs. Depleting fossil resources will gradually be replaced by …
Vibrational properties of boroxine anhydride and boronate ester materials: model systems for the diagnostic characterization of covalent organic frameworks
MK Smith, BH Northrop - Chemistry of Materials, 2014 - ACS Publications
The vibrational characteristics of 28 different boronic acid, boroxine anhydride, and boronate
ester species have been systematically investigated using a combination of experimental …
ester species have been systematically investigated using a combination of experimental …
Direct Arylation/Alkylation/Magnesiation of Benzyl Alcohols in the Presence of Grignard Reagents via Ni-, Fe-, or Co-Catalyzed sp3 C–O Bond Activation
DG Yu, X Wang, RY Zhu, S Luo, XB Zhang… - Journal of the …, 2012 - ACS Publications
Direct application of benzyl alcohols (or their magnesium salts) as electrophiles in various
reactions with Grignard reagents has been developed via transition metal-catalyzed sp3 C …
reactions with Grignard reagents has been developed via transition metal-catalyzed sp3 C …
Activation of diverse carbon–heteroatom and carbon–carbon bonds via palladium(ii)-catalysed β-X elimination
Chemists' ability to synthesize structurally complex, high-value organic molecules from
simple starting materials is limited by methods to selectively activate and functionalize strong …
simple starting materials is limited by methods to selectively activate and functionalize strong …
1, 3-Dicyclohexylimidazol-2-ylidene as a superior ligand for the nickel-catalyzed cross-couplings of aryl and benzyl methyl ethers with organoboron reagents
M Tobisu, A Yasutome, H Kinuta, K Nakamura… - Organic …, 2014 - ACS Publications
A new catalytic system has been developed involving the use of Ni (cod) 2 in conjunction
with 1, 3-dicyclohexylimidazol-2-ylidene for the cross-coupling of aryl and benzyl methyl …
with 1, 3-dicyclohexylimidazol-2-ylidene for the cross-coupling of aryl and benzyl methyl …
Etheric C–O bond hydrogenolysis using a tandem lanthanide triflate/supported palladium nanoparticle catalyst system
Selective hydrogenolysis of cyclic and linear ether C–O bonds is accomplished by a tandem
catalytic system consisting of lanthanide triflates and sinter-resistant supported palladium …
catalytic system consisting of lanthanide triflates and sinter-resistant supported palladium …
Vinylpyridines as Building Blocks for the Photocatalyzed Synthesis of Alkylpyridines
The photocatalyzed addition of several hydrogen donors (ethers, aldehydes, alkanes,
amides) onto vinylpyridines was achieved. This approach provided access to alkylpyridines …
amides) onto vinylpyridines was achieved. This approach provided access to alkylpyridines …
Iridium-catalyzed alkylation of methylquinolines with alcohols
Y Obora, S Ogawa, N Yamamoto - The Journal of Organic …, 2012 - ACS Publications
Iridium-catalyzed alkylation of methylquinolines at the methyl substituent was achieved
using alcohols as alkylating agents. The reaction proceeded through a transfer …
using alcohols as alkylating agents. The reaction proceeded through a transfer …
Practical cross-coupling between O-based electrophiles and aryl bromides via Ni catalysis
ZC Cao, QY Luo, ZJ Shi - Organic letters, 2016 - ACS Publications
Cross-coupling of various O-based electrophiles with aryl bromides was developed through
Ni-catalyzed C–O activation in the presence of magnesium. Beside carboxylates …
Ni-catalyzed C–O activation in the presence of magnesium. Beside carboxylates …