Recent development in catalytic application of transition metal complexes having an M–E
bond (E= main group metal or metalloid element), which is stabilized by a multidentate …

A commitment to developing a convenient, efficient, and safe hydrogenation strategy is one
of the main focuses of industry and academia. Electrochemical hydrogenation brings …

Despite widespread use of the deuterium isotope effect, selective deuterium labeling of
chemical molecules remains a major challenge. Herein, a facile and general …

An efficient additive-free manganese-catalyzed hydrogenation of alkenes to alkanes with
molecular hydrogen is described. This reaction is atom economic, implementing an …

The selective semihydrogenation of alkynes to (E)-alkenes is a challenging transformation
that is of significant synthetic interest. The development of direct hydrogenation catalysts for …

An iron catalyst has been developed for the transfer hydrogenation of carbon–carbon
multiple bonds. Using a well-defined β-diketiminate iron (II) precatalyst, a sacrificial amine …

Transition-metal complexes with Si–M bonds are important catalysts for hydrosilylation and
hydrogenation reactions. However, the function of the ligated silicon atom in the …

Electrochemical hydrogenation of unsaturated organic compounds is emerging as a very
promising alternative to the conventional transition-metal-catalyzed transformation as it …

Two synthetic approaches have until now been used to synthesize transition metal
complexes having a tridentate (pincer or tripod) PEP tetryl (E= Si, Ge, Sn) ligand. These …

Efficient hydrogenations of terminal alkenes with molecular hydrogen catalyzed by well‐
defined bench stable Mn (I) complexes containing an N‐heterocyclic carbene‐based PCP …